3-vinylbiphenyl

Base Information

• Chemical Name: 3-vinylbiphenyl
• CAS No.: 38383-51-6
• Molecular Formula: C14H12
• Molecular Weight: 180.249
• Mol file: 38383-51-6.mol

Synonyms:3-vinylbiphenyl;1,1'-Biphenyl,3-ethenyl;m-phenylstyrene;

Chemical Property of 3-vinylbiphenyl

Chemical Property:

• PSA: 0.00000
• LogP: 3.99660
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

1-Ethenyl-3-phenylbenzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-vinylbiphenyl

There total 11 articles about 3-vinylbiphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

-butyl vinyl ether (111-34-2,92680-80-3) + biphenyl-2-yl-lithium (55365-18-9) → 3-vinyl-1,1'-biphenyl (38383-51-6)

Guidance literature:

-butyl vinyl ether; biphenyl-2-yl-lithium; With zirconocene methyl chloride; In tetrahydrofuran; at -78 - 80 ℃; for 3.5h;

With water; In tetrahydrofuran; at 20 ℃; for 1h;

DOI:10.1055/s-2005-872699

Reference yield: 91.0%

vinyl acetate (108-05-4,9003-20-7) + 3-bromobiphenyl (2113-57-7) → 3-vinyl-1,1'-biphenyl (38383-51-6)

Guidance literature:

With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); lithium iodide; zinc; at 65 ℃; for 8h; Inert atmosphere; Sealed tube; Green chemistry;

DOI:10.1021/acs.orglett.1c04018

Reference yield: 86.0%

vinyl acetate (108-05-4,9003-20-7) + 3-Biphenylboronic acid (5122-95-2) → 3-vinyl-1,1'-biphenyl (38383-51-6)

Guidance literature:

With 1,3-bis-(diphenylphosphino)propane; palladium diacetate; In N,N-dimethyl-formamide; at 150 ℃; for 0.0333333h;

DOI:10.1002/ejoc.201000063

upstream raw materials:

(RS)-1-([1,1'-biphenyl]-3-yl)ethanol

-butyl vinyl ether

biphenyl-2-yl-lithium

[(1,1'-biphenyl)-3-yl]magnesium bromide

Downstream raw materials:

(E)-2-(2-([1,1'-biphenyl]-3-yl)vinyl)benzo[d]oxazole