4-(3-Methyl-2-methylidenebut-3-en-1-yl)morpholine

Base Information

• Chemical Name: 4-(3-Methyl-2-methylidenebut-3-en-1-yl)morpholine
• CAS No.: 38644-64-3
• Molecular Formula: C10H17NO
• DSSTox Substance ID: DTXSID00513327
• Wikidata: Q82373083
• Mol file: 38644-64-3.mol

Synonyms:38644-64-3;4-(3-Methyl-2-methylidenebut-3-en-1-yl)morpholine;(2,3-dimethylenebutyl)morpholine;DTXSID00513327

Chemical Property of 4-(3-Methyl-2-methylidenebut-3-en-1-yl)morpholine

Chemical Property:

• XLogP3: 2.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 167.131014166
• Heavy Atom Count: 12
• Complexity: 180

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=C)CN1CCOCC1

Technology Process of 4-(3-Methyl-2-methylidenebut-3-en-1-yl)morpholine

There total 2 articles about 4-(3-Methyl-2-methylidenebut-3-en-1-yl)morpholine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

morpholine (110-91-8,99108-56-2) + 1,2-propanediene (463-49-0) → N-allylmorpholine (696-57-1) + N-(2,3-dimethylenebutyl)morpholine (38644-64-3)

Guidance literature:

With triphenylphosphine; trifluoroacetic acid; palladium dichloride; In N,N-dimethyl-formamide; at 92 ℃; for 0.5h; under 5400430 Torr;

DOI:10.1007/BF00952390

Reference yield:

→ N-(2,3-dimethylenebutyl)morpholine (38644-64-3)

Guidance literature:

Allen, Morpholin, NiBr2/Ph(i-PrO)2P;

DOI:10.1039/c39730000472

upstream raw materials:

morpholine

1,2-propanediene