SILICON PHTHALOCYANINE DICHLORIDE

Base Information

• Chemical Name: SILICON PHTHALOCYANINE DICHLORIDE
• CAS No.: 19333-10-9
• Molecular Formula: C32H16Cl2N8Si
• Molecular Weight: 611.524
• Mol file: 19333-10-9.mol

Synonyms:Silicon,dichloro[29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, (OC-6-12)-;Silicon,dichloro[phthalocyaninato(2-)]- (7CI,8CI);Dichloro(phthalocyaninato)silicon;Dichloro(phthalocyanino)silicon;Dichloro[phthalocyaninato(2-)]silicon;Dichlorophthalocyaninatosilane;Dichlorophthalocyanosilane;Dichlorosilicon phthalocyanine;Siliconphthalocyanine dichloride;

Chemical Property of SILICON PHTHALOCYANINE DICHLORIDE

Chemical Property:

• Appearance/Colour: DARK BLUE, VIOLET OR BLACK POWDER
• Melting Point: 430 °C (subl.)
• Refractive Index: 1.88
• Flash Point: >200 °C
• PSA: 84.02000
• Density: 1.65 g/cm³
• LogP: 2.46260

Purity/Quality:

99% ^*data from raw suppliers

Silicon(IV) phthalocyanine dichloride, 85% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Precursor to stacked-ring silicon phthalocyanines.

Technology Process of SILICON PHTHALOCYANINE DICHLORIDE

There total 13 articles about SILICON PHTHALOCYANINE DICHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

isoindole-1,3-diylidenediamine (160956-25-2,160956-26-3,160956-27-4,160956-28-5,160956-29-6) → phthalocyanine silicon(IV) dichloride (19333-10-9)

Guidance literature:

With quinoline; tetrachlorosilane; at 210 - 220 ℃; for 1h; Inert atmosphere;

Reference yield: 88.0%

tetrachlorosilane (10026-04-7,53609-55-5) + phthalonitrile (91-15-6) → phthalocyanine silicon(IV) dichloride (19333-10-9)

Guidance literature:

phthalonitrile; With sodium methylate; In methanol; at 20 ℃; for 0.25h; Inert atmosphere;

With ammonia; In methanol; for 1h; Reflux;

tetrachlorosilane; With quinoline; at 25 - 221 ℃; Inert atmosphere;

Reference yield: 86.0%

1-amino-3-imino-isoindoline + tetrachlorosilane (10026-04-7,53609-55-5) → phthalocyanine silicon(IV) dichloride (19333-10-9)

Guidance literature:

With quinoline; at 40 - 219 ℃; for 6.75h;

upstream raw materials:

isoindole-1,3-diylidenediamine

phthalonitrile

tetrachlorosilane

C₁₉H₂₁N₃O₃

Downstream raw materials:

bis(tri-n-hexylsilyl oxide) silicon phthalocyanine

bis(tri-n-butylsilyl oxide) silicon phthalocyanine

silicon phthalocyanine tri-n-butylsilyl oxide tri-n-hexylsilyl oxide

silicon phthalocyanine bis(triphenylsilyl oxide)

Refernces

• 1、 Chen, Juan-Juan,Huang, Yi-Zhen,Song, Mei-Ru,Zhang, Zhi-Hong,Xue, Jin-Ping. "Silicon Phthalocyanines Axially Disubstituted with Erlotinib toward Small-Molecular-Target-Based Photodynamic Therapy". . p. 1504 - 1511. Retrieved 2017.
• 2、 Park, Ha Sun,Ryu, Haiil,Jang, Nak Han. "Synthesis and characterization of phthalocyaninatosilicon with bridging ligands (L) (L = Dimethylsilane, diphenylsilane, methylphenylsilane)". . p. 207 - 212. Retrieved 2016.
• 3、 Kojima, Yuko,Osano, Yasuko T.,Ohashi, Toyoshi. "Ab-initio X-ray powder structure analysis of two polymorphs of dihydroxysilicon phthalocyanine". . p. 2203 - 2210. Retrieved 1999.
• 4、 -. "Water-soluble mitochondrial targeting ethoxy-bromopropyl imidazole axial substituted silicon phthalocyanine and preparation method and application thereof". Paragraph 0016. . Retrieved 2021/10/05.
• 5、 Xiao, Shuanghuang,Chen, Xiuqin,Ye, Qiuhao,Chen, Kuizhi,Xiao, Wenling,Guan, Xinqiao,Huang, Bingcheng,Liu, Guowei,Wei, Hui,Peng, Yiru. "Prop-2-ynyloxybenzyloxy substituted phthalocyanine-based polymeric nanoparticles: synthesis, photophysical properties and in?vitro PDT efficacy". . p. 1232 - 1244. Retrieved 2020/06/17.