1,1'-Biphenyl, 2-iodo-2-methyl-

Base Information

• Chemical Name: 1,1'-Biphenyl, 2-iodo-2-methyl-
• CAS No.: 39655-09-9
• Molecular Formula: C13H11I
• Molecular Weight: 294.135
• Mol file: 39655-09-9.mol

Synonyms:1,1'-Biphenyl,2-iodo-2-methyl;2-Iod-2'-methylbiphenyl;2-iodo-2'-methylbiphenyl;2-Jod-2'-methylbiphenyl;

Chemical Property of 1,1'-Biphenyl, 2-iodo-2-methyl-

Chemical Property:

• Melting Point: 38-39 °C
• Boiling Point: 186-187 °C
• PSA: 0.00000
• Density: 1.523±0.06 g/cm3(Predicted)
• LogP: 4.22360

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,1'-Biphenyl, 2-iodo-2-methyl-

There total 12 articles about 1,1'-Biphenyl, 2-iodo-2-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

ortho-tolylmagnesium bromide (932-31-0) + 1-Bromo-2-iodobenzene (583-55-1) → 2-iodo-2’-methylbiphenyl (39655-09-9)

Guidance literature:

ortho-tolylmagnesium bromide; 1-Bromo-2-iodobenzene; In tetrahydrofuran; at 20 ℃; for 14h;

With iodine; In tetrahydrofuran; at 20 ℃; for 0.5h; Further stages.;

DOI:10.1021/ja069238z

Reference yield: 66.0%

1-Bromo-2-iodobenzene (583-55-1) + 2-methylphenyl bromide (95-46-5) → 2-iodo-2’-methylbiphenyl (39655-09-9)

Guidance literature:

2-methylphenyl bromide; With magnesium; In tetrahydrofuran;

1-Bromo-2-iodobenzene; In tetrahydrofuran; at 20 ℃; for 14h;

DOI:10.1021/jo0619534

Reference yield:

2-(2-methylphenyl)aniline (1203-41-4) → 2-iodo-2’-methylbiphenyl (39655-09-9)

Guidance literature:

With hydrogenchloride; Diazotization_.Behandlung der Diazoniumsalz-Loesung mit KI;

upstream raw materials:

2-(2-methylphenyl)aniline

ortho-methylphenyl iodide

2-iodochlorobenzene

ortho-nitrobenzoic acid

Downstream raw materials:

2,4''''-Dimethyl-1:1',2':1'',3'':1''',2''':1''''-quinquephenyl

2,2''''-Dimethyl-1,1':2',1'':3'',1''':2''',1''''-quinquephenyl

1-methyltriphenylene

4-methylfluorene