Benzonitrile, 4-[2-(1-pyrenyl)ethyl]-

Base Information

• Chemical Name: Benzonitrile, 4-[2-(1-pyrenyl)ethyl]-
• CAS No.: 400822-57-3
• Molecular Formula: C25H17N
• Molecular Weight: 331.417
• Mol file: 400822-57-3.mol

Synonyms:

Chemical Property of Benzonitrile, 4-[2-(1-pyrenyl)ethyl]-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzonitrile, 4-[2-(1-pyrenyl)ethyl]-

There total 2 articles about Benzonitrile, 4-[2-(1-pyrenyl)ethyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

4-[2-(pyren-1-yl)vinyl]benzonitrile → 4-(2-pyren-1-yl-ethyl)-benzonitrile (400822-57-3)

Guidance literature:

With magnesium; 10percent Pd/C; In propan-1-ol; for 24h; Heating;

DOI:10.1002/1099-0690(200110)2001:20<3819::AID-EJOC3819>3.0.CO;2-W

Reference yield:

4-bromobenzenecarbonitrile (623-00-7) + 1-vinylpyrene (17088-21-0) → 4-(2-pyren-1-yl-ethyl)-benzonitrile (400822-57-3)

Guidance literature:

1-vinylpyrene; With 9-borabicyclo[3.3.1]nonane dimer; In tetrahydrofuran; at 20 ℃; for 8h;

4-bromobenzenecarbonitrile; With sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; for 16h; Further stages.; Heating;

DOI:10.1002/1099-0690(200110)2001:20<3819::AID-EJOC3819>3.0.CO;2-W

Reference yield:

Dichloromethyl methyl ether (4885-02-3) + 4-(2-pyren-1-yl-ethyl)-benzonitrile (400822-57-3) → 1-chloromethyl-8-[2-(4-cyanophenyl)-ethyl]-pyrene + 1-chloromethyl-6-[2-(4-cyanophenyl)-ethyl]-pyrene

Guidance literature:

Dichloromethyl methyl ether; 4-(2-pyren-1-yl-ethyl)-benzonitrile; With titanium tetrachloride; In dichloromethane; at 20 ℃;

With sodium tetrahydroborate; In tetrahydrofuran; isopropyl alcohol; at 20 ℃;

With thionyl chloride; In dichloromethane; at 20 ℃; Title compound not separated from byproducts;

DOI:10.1021/jo050302p

upstream raw materials:

4-bromobenzenecarbonitrile

1-vinylpyrene

Refernces