3,5-Hexadienoic acid, methyl ester

Base Information

Chemical Name:3,5-Hexadienoic acid, methyl ester
CAS No.:40338-61-2
Molecular Formula:C7H10O2
Molecular Weight:126.155
Hs Code.:
Mol file:40338-61-2.mol

Synonyms:methyl 3,5-hexadienoate;methyl hexa-3,5-dienoate;Hexadien-(3,5)-saeure-methylester;Methyl-3,5-hexadienoat;(E)-Hexa-3,5-dienoic acid methyl ester;

Suppliers and Price of 3,5-Hexadienoic acid, methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3,5-Hexadienoic acid, methyl ester

Chemical Property:

Boiling Point:66 - 68 °C (17 mmHg)
PSA：26.30000
LogP:1.29170

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 3,5-Hexadienoic acid, methyl ester

There total 1 articles about 3,5-Hexadienoic acid, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 67-56-1
methanol

: 90554-82-8
hexa-2,4-dienoyl chloride

: 1515-80-6
sorbic acid methyl ester

: 40338-61-2
3,5-Hexadiensaeure-methylester

Guidance literature:: With triethylamine; In dichloromethane; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

Reference yield:

: 40338-61-2
3,5-Hexadiensaeure-methylester

: 97673-91-1
C₂₀H₂₀O₃Se

Guidance literature:: Multi-step reaction with 10 steps

1: 95 percent / 24 h / 55 °C

2: TsOH / CH₂Cl₂ / 0.33 h / 0 °C

3: 99 percent / NaBH₄ / methanol / 0.5 h / -40 °C

4: Et₃N, 4-(dimethylamino)pyridine / CH₂Cl₂ / 2 h / Ambient temperature

5: 1 N aq. HCl / methanol / 1 h / Ambient temperature

6: 79 percent / K₂CO₃ / CH₂Cl₂ / 4 h

7: 63 percent / 1 N aq. NaOH / methanol / 2 h / Ambient temperature

8: 63 percent / TsOH / tetrahydrofuran; benzene / 12 h / Heating

9: 94 percent / LiAlH₄, t-BuOH / tetrahydrofuran; diethyl ether / 0.25 h / 0 °C

10: 1.) TsOH, 3.) 1 N aq. HCl

With hydrogenchloride; dmap; sodium hydroxide; sodium tetrahydroborate; lithium aluminium tetrahydride; potassium carbonate; toluene-4-sulfonic acid; triethylamine; tert-butyl alcohol; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; benzene;
DOI:10.1021/jo00221a019

Reference yield:

: 40338-61-2
3,5-Hexadiensaeure-methylester

: 97654-97-2
C₂₀H₂₀O₄Se

Guidance literature:: Multi-step reaction with 10 steps

1: 95 percent / 24 h / 55 °C

2: TsOH / CH₂Cl₂ / 0.33 h / 0 °C

3: 99 percent / NaBH₄ / methanol / 0.5 h / -40 °C

4: Et₃N, 4-(dimethylamino)pyridine / CH₂Cl₂ / 2 h / Ambient temperature

5: 1 N aq. HCl / methanol / 1 h / Ambient temperature

6: 79 percent / K₂CO₃ / CH₂Cl₂ / 4 h

7: 63 percent / 1 N aq. NaOH / methanol / 2 h / Ambient temperature

8: 63 percent / TsOH / tetrahydrofuran; benzene / 12 h / Heating

9: 94 percent / LiAlH₄, t-BuOH / tetrahydrofuran; diethyl ether / 0.25 h / 0 °C

10: TsOH / benzene / Heating

With hydrogenchloride; dmap; sodium hydroxide; sodium tetrahydroborate; lithium aluminium tetrahydride; potassium carbonate; toluene-4-sulfonic acid; triethylamine; tert-butyl alcohol; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; benzene;
DOI:10.1021/jo00221a019