Hydroperoxide, 1-methyl-1-(2-phenyloxiranyl)ethyl

Base Information

• Chemical Name: Hydroperoxide, 1-methyl-1-(2-phenyloxiranyl)ethyl
• CAS No.: 403731-50-0
• Molecular Formula: C11H14O3
• Molecular Weight: 194.23
• Mol file: 403731-50-0.mol

Synonyms:

Chemical Property of Hydroperoxide, 1-methyl-1-(2-phenyloxiranyl)ethyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Hydroperoxide, 1-methyl-1-(2-phenyloxiranyl)ethyl

There total 3 articles about Hydroperoxide, 1-methyl-1-(2-phenyloxiranyl)ethyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

α,β,β-trimethylstyrene (769-57-3) → 1-(2-Methyl-oxiranyl)-1-phenyl-eth-1-yl-hydroperoxide + 1-methyl-1-(2-phenyloxiran-2-yl)ethyl hydroperoxide (403731-50-0)

Guidance literature:

α,β,β-trimethylstyrene; With oxygen; 5,15,10,20-tetraphenylporphyrin; In dichloromethane; at -20 ℃; for 22h; Irradiation;

With peracetic acid; sodium acetate; In dichloromethane; acetic acid; at 20 ℃; for 72h; Further stages.;

DOI:10.1021/ol017138m

Reference yield:

1,2-dimethyl-1-phenyl-1-propanol (62837-59-6,62837-77-8,139561-50-5,4383-11-3) → 1-methyl-1-(2-phenyloxiran-2-yl)ethyl hydroperoxide (403731-50-0)

Guidance literature:

Multi-step reaction with 2 steps

1.1: sulfuric acid; acetic acid / 0.07 h / 60 °C

2.1: singlet O₂; tetraphenylporphin / CH₂Cl₂ / 22 h / -20 °C / Irradiation

2.2: 38 percent / peracetic acid; sodium acetate / CH₂Cl₂; acetic acid / 72 h / 20 °C

With oxygen; sulfuric acid; 5,15,10,20-tetraphenylporphyrin; acetic acid; In dichloromethane;

DOI:10.1021/ol017138m

Reference yield:

acetophenone (98-86-2) → 1-methyl-1-(2-phenyloxiran-2-yl)ethyl hydroperoxide (403731-50-0)

Guidance literature:

Multi-step reaction with 3 steps

1.1: magnesium / diethyl ether / 1 h / Heating

1.2: diethyl ether

2.1: sulfuric acid; acetic acid / 0.07 h / 60 °C

3.1: singlet O₂; tetraphenylporphin / CH₂Cl₂ / 22 h / -20 °C / Irradiation

3.2: 38 percent / peracetic acid; sodium acetate / CH₂Cl₂; acetic acid / 72 h / 20 °C

With oxygen; sulfuric acid; 5,15,10,20-tetraphenylporphyrin; magnesium; acetic acid; In diethyl ether; dichloromethane; 1.1: Grignard reaction;

DOI:10.1021/ol017138m

upstream raw materials:

α,β,β-trimethylstyrene

1,2-dimethyl-1-phenyl-1-propanol

acetophenone

Downstream raw materials:

3,3-dimethyl-4-hydroxymethyl-4-phenyl-1,2-dioxetane