Sulfuryl chloride fluoride

Base Information

• Chemical Name: Sulfuryl chloride fluoride
• CAS No.: 13637-84-8
• Deprecated CAS: 73571-19-4
• Molecular Formula: ClF O2 S
• Molecular Weight: 118.516
• European Community (EC) Number: 237-126-2
• UNII: Y7TT1LZ9SD
• DSSTox Substance ID: DTXSID0065567
• Nikkaji Number: J101.060C
• Wikipedia: Sulfuryl_chloride_fluoride
• Wikidata: Q3074520
• Mol file: 13637-84-8.mol

Synonyms:SULFURYL CHLORIDE FLUORIDE;13637-84-8;Chlorosulfonyl fluoride;Sulfonyl chloride fluoride;Chloro fluoro sulfone;Fluorosulfonyl chloride;Sulfuryl chlorofluoride;Sulfuryl fluorochloride;Chlorosulphonyl fluoride;Sulfuryl fluoride chloride;TL 212;SO2ClF;SO2FCl;Fluorosulfuryl chloride;EINECS 237-126-2;Y7TT1LZ9SD;AI3-27293;chlorofluorodioxosulfur;ClFO2S;SClFO2;UNII-Y7TT1LZ9SD;[SClFO2];Sulphuryl chloride fluoride;chloridofluoridodioxidosulfur;Cl-F-O2-S;DTXSID0065567;CHEBI:39445;Sulphuryl chloride fluoride 97%;MFCD00011607;LS-148267;FT-0693957;A807071;Q3074520;Sulfuryl chloride fluoride, technical grade, >=90%

Chemical Property of Sulfuryl chloride fluoride

Chemical Property:

• Appearance/Colour: clear colorless to light yellow liquid
• Vapor Pressure: 1420mmHg at 25°C
• Melting Point: -125ºC
• Refractive Index: 1.391
• Boiling Point: 7 ºC
• Flash Point: °C
• PSA: 42.52000
• Density: 1.784 g/cm³
• LogP: 1.52030
• Storage Temp.: ?20°C
• Sensitive.: Moisture Sensitive
• XLogP3: 0.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 117.9291563
• Heavy Atom Count: 5
• Complexity: 95.3

Purity/Quality:

99% ^*data from raw suppliers

Sulfuryl chlorofluoride 90% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T,C
• Statements: 14-23/24/25-34
• Safety Statements: 26-27-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Toxic Gases & Vapors -> Corrosive Gases
• Canonical SMILES: O=S(=O)(F)Cl

Technology Process of Sulfuryl chloride fluoride

There total 23 articles about Sulfuryl chloride fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

sulfur dioxide (7446-09-5,12143-17-8,89125-89-3) + chlorine monofluoride (7790-89-8) → fluorosulfonylchloride (13637-84-8)

Guidance literature:

byproducts: Cl2, SO2F2; in an autoclave, warming from -196 to -78°C, then to 20°C;

DOI:10.1021/ic50084a027

Reference yield: 90.0%

sulfuryl dichloride (7791-25-5) + antimony(III) fluoride (7783-56-4) → fluorosulfonylchloride (13637-84-8)

Guidance literature:

antimony(V) chloride; water; In neat (no solvent);

Reference yield: 85.6%

tri-n-butylamine * 2.6 (hydrofluoride) + sulfuryl dichloride (7791-25-5) → fluorosulfonyl fluoride (640723-20-2,2699-79-8,12769-73-2) + fluorosulfonylchloride (13637-84-8)

Guidance literature:

at 20 ℃;

upstream raw materials:

sulfuryl dichloride

tributyl-amine

trifluoroacetic acid

hydrogen fluoride

Downstream raw materials:

acetosulfam

2-ethenylbenzenesulfonamide

antimony(III) fluoride

N,N-diethylsulfamoyl chloride

Refernces

• 1、 -. "Method of producing acid fluorides from acid chlorides". Page column 6. . Retrieved 2008/06/13.
• 2、 Roderiguez, Joseph A.,Noftle, Ronald E.. "The reaction of fluorosulfuryl isocyanate with alkali metal fluorides". . p. 1874 - 1877. Retrieved 2008/10/08.