7790-89-8Relevant articles and documents
Wilkins, J. W.,Gabriel, J. R.
, p. 1950 - 1957 (1963)
Farrar, R. L.,Smith, H. A.
, p. 763 - 768 (1955)
From hypochlorites to perfluorinated dialkyl peroxides
Nissen, Jan H.,Wickemeyer, Lucas,Stüker, Tony,Steinhauer, Simon,Beckers, Helmut,Riedel, Sebastian
supporting information, (2019/12/26)
The synthesis and characterization of the new perfluorinated hypochlorite, undecafluoro-tert-pentyl hypochlorite, (C2F5)(F3C)2COCl, is reported. Its gas-phase infrared, UV/Vis and NMR spectra have been recorded and its spectroscopic properties are discussed and compared with quantum-chemical predictions and those of other known perfluorinated hypochlorites such as RFOCl [RF = F3C, (F3C)3C, (C2F5)(F3C)2C]. A synthetic route to otherwise difficult to access perfluorinated dialkyl peroxides, RFOORF, is also provided by low-temperature photolysis of the corresponding hypochlorite.
Temperature Dependence of the Rate Constant for the Reaction F( 2P) + Cl2 → FCl + Cl at T = 180-360 K
Nesbitt, Fred L.,Cody, Regina J.,Dalton, Douglas A.,Riffault, Veronique,Bedjanian, Yuri,Le Bras, Georges
, p. 1726 - 1730 (2007/10/03)
The absolute rate constant for the reaction F(2P) with Cl 2 has been measured using the discharge flow kinetics technique coupled to mass spectrometric detection at T = 180-360 K and 1 Torr He nominal pressure. Experiments were performed at NASA Goddard Space Flight Center (GSFC) in Greenbelt, MD, and Laboratoire de Combustion et Systemes Reactifs-CNRS in Orleans, France. Results of k = (5.7 ± 0.8) × 10-11 and (6.2 ± 0.8) × 10-11 cm3 molecule-1 s-1 independent of temperature were obtained by each laboratory, respectively. When the results from both laboratories were combined into one data set, an average temperature independent value of k1 = (6.0 ± 1.1) × 10-11 cm3 molecule-1 s-1 was obtained. A very slight positive temperature dependence with k1(T) = (6.5 ± 1.5) × 10-11 exp{-(20 ± 60)/T} cm3 molecule-1 s-1 may also be derived from the combined data in the range T = 180-360 K.
