Fluoro-dimethyl-(2-phenylethynyl)silane

Base Information

• Chemical Name: Fluoro-dimethyl-(2-phenylethynyl)silane
• CAS No.: 42591-61-7
• Molecular Formula: C10H11FSi
• Molecular Weight: 178.281
• DSSTox Substance ID: DTXSID30473066
• Nikkaji Number: J823.701H
• Mol file: 42591-61-7.mol

Synonyms:Fluoro-dimethyl-(2-phenylethynyl)silane;42591-61-7;DTXSID30473066;fluorodimethyl(phenylethynyl)silane

Chemical Property of Fluoro-dimethyl-(2-phenylethynyl)silane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 178.06140505
• Heavy Atom Count: 12
• Complexity: 202

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C[Si](C)(C#CC1=CC=CC=C1)F

Technology Process of Fluoro-dimethyl-(2-phenylethynyl)silane

There total 3 articles about Fluoro-dimethyl-(2-phenylethynyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chlorodimethyl(phenylethynyl)silane (42591-54-8) → Dimethyl(phenylethinyl)fluorsilan (42591-61-7)

Guidance literature:

With hydrogen fluoride; In ethanol; for 7h; Ambient temperature;

DOI:10.1016/0022-328X(85)80199-6

Reference yield:

dimethylmonochlorosilane (1066-35-9) + phenylacetylene (536-74-3) → Dimethyl(phenylethinyl)fluorsilan (42591-61-7)

Guidance literature:

With copper (II)-fluoride; n-butyllithium; Yield given. Multistep reaction; 1.) THF, hexane, room temperature, 10 min;

DOI:10.1016/S0040-4020(97)00043-4

Reference yield:

→ Dimethyl(phenylethinyl)fluorsilan (42591-61-7)

Guidance literature:

DOI:10.1007/BF00928632

upstream raw materials:

chlorodimethyl(phenylethynyl)silane

dimethylmonochlorosilane

phenylacetylene

Downstream raw materials:

1,3-diphenyl-2-propynone

diphenyl acetylene

(E)-1,5-diphenyl-1-penten-4-yn-3-one

3-phenyl-1-(2-thienyl)-2-propyn-1-one