Benzamide, N-(2-propenyloxy)-

Base Information

• Chemical Name: Benzamide, N-(2-propenyloxy)-
• CAS No.: 42832-36-0
• Molecular Formula: C10H11NO2
• Molecular Weight: 177.203
• ChEMBL ID: CHEMBL3627902
• DSSTox Substance ID: DTXSID90481788
• Nikkaji Number: J1.682.502F
• Wikidata: Q82317416
• Mol file: 42832-36-0.mol

Synonyms:O-allyl-N-benzoyl-hydroxylamine;N-allyloxy-benzamide;N-Benzoyl-O-allylhydroxylamine;N-Benzoyl-O-allyl-hydroxylamin;N-Allyloxy-benzamid;Allylbenzohydroxaminsaeure;

Chemical Property of Benzamide, N-(2-propenyloxy)-

Chemical Property:

• PSA: 41.82000
• LogP: 2.10880
• XLogP3: 0.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 177.078978594
• Heavy Atom Count: 13
• Complexity: 174

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCONC(=O)C1=CC=CC=C1

Technology Process of Benzamide, N-(2-propenyloxy)-

There total 8 articles about Benzamide, N-(2-propenyloxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

O-allylhydroxylamine hydrochloride (38945-21-0) + benzoyl chloride (98-88-4) → N-Benzoyl-O-allylhydroxylamine (42832-36-0)

Guidance literature:

With sodium carbonate; In water; benzene; at 20 ℃; for 18h; Cooling;

DOI:10.1055/s-0031-1290384

Reference yield: 93.0%

O-Allylhydroxylamine (6542-54-7) + benzoic acid (65-85-0,8013-63-6) → N-Benzoyl-O-allylhydroxylamine (42832-36-0)

Guidance literature:

benzoic acid; With N-ethyl-N,N-diisopropylamine; chlorophosphoric acid diphenyl ester; In N,N-dimethyl-formamide; at 0 ℃; for 0.166667h;

O-Allylhydroxylamine; In N,N-dimethyl-formamide; at 20 ℃; for 0.833333h; Further stages.;

DOI:10.1002/jhet.5570450406

Reference yield: 55.0%

potassium benzohydroxamate (32685-16-8) + allyl bromide (106-95-6) → N-Benzoyl-O-allylhydroxylamine (42832-36-0)

Guidance literature:

tetra-(n-butyl)ammonium iodide; In water; chlorobenzene; at 70 - 75 ℃; for 14h; phase transfer catalysis;

upstream raw materials:

Benzohydroxamic acid

allyl bromide

potassium benzohydroxamate

O-Allylhydroxylamine

Downstream raw materials:

O-allylhydroxylamine hydrochloride

O-Allylbenzohydroximoyl chloride

C₁₇H₁₆N₂O₂S

N-Propionyl-S-benzoyl-2-mercapto-benzylamin