Acetic acid, oxo(triethylsilyl)-, phenylmethyl ester

Base Information

Chemical Name:Acetic acid, oxo(triethylsilyl)-, phenylmethyl ester
CAS No.:443988-54-3
Molecular Formula:C15H22O3Si
Molecular Weight:278.423
Hs Code.:
DSSTox Substance ID:DTXSID60479511
Nikkaji Number:J1.757.980K
Wikidata:Q82313591

Synonyms:Acetic acid, oxo(triethylsilyl)-, phenylmethyl ester;443988-54-3;DTXSID60479511

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Acetic acid, oxo(triethylsilyl)-, phenylmethyl ester

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:8
Exact Mass:278.13382109
Heavy Atom Count:19
Complexity:296

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC[Si](CC)(CC)C(=O)C(=O)OCC1=CC=CC=C1

Technology Process of Acetic acid, oxo(triethylsilyl)-, phenylmethyl ester

There total 2 articles about Acetic acid, oxo(triethylsilyl)-, phenylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 443988-47-4
benzyl 2-triethylsilyl-2-diazoacetate

: 443988-54-3
benzyl 2-triethylsilyl-2-oxoacetate

Guidance literature:: With dirhodium tetraacetate; methyloxirane; In toluene; at 40 ℃;
DOI:10.1021/ol025911n

Reference yield:

: 52267-51-3
benzyl diazoacetate

: 443988-54-3
benzyl 2-triethylsilyl-2-oxoacetate

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / ethyldiisopropylamine / diethyl ether

2: 89 percent / propylene oxide; [Rh₂(OAc)4] / toluene / 40 °C

With dirhodium tetraacetate; N-ethyl-N,N-diisopropylamine; methyloxirane; In diethyl ether; toluene;
DOI:10.1021/ol025911n