Gold, [2,6-bis[(dimethylamino)methyl]phenyl](triphenylphosphine)-

Base Information

Chemical Name:Gold, [2,6-bis[(dimethylamino)methyl]phenyl](triphenylphosphine)-
CAS No.:474888-54-5
Molecular Formula:C30H34AuN2P
Molecular Weight:650.554
Hs Code.:

Synonyms:

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Chemical Property of Gold, [2,6-bis[(dimethylamino)methyl]phenyl](triphenylphosphine)-

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:: SDS file from LookChem

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Technology Process of Gold, [2,6-bis[(dimethylamino)methyl]phenyl](triphenylphosphine)-

There total 2 articles about Gold, [2,6-bis[(dimethylamino)methyl]phenyl](triphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 14243-64-2
(triphenylphosphine)gold(I) chloride

: 19851-44-6
1,3-bis[(dimethylamino)methyl]benzene

: 474888-54-5
[Au(C₆H₃(CH₂NMe₂)2-2,6)(triphenylphosphine)]

Guidance literature:: With n-C₄H₉Li; In diethyl ether; hexane; pentane; byproducts: LiCl; (N2); using Schlenk techniques; addn. of soln. n-C4H9Li in C6H14 to soln. of C6H3(CH2NMe2)2 (1 equiv.) in C5H12; stirring for 16 h; addn. to suspn. of AuClPPh3 (1 equiv.) in Et2O at -30°C; stirring for 15 min,stirring for 4.5 h at room temp.; quenching with water, filtration, sepn. of org. fraction, extn. of aq. fraction with diethyl ether, combining of extracts, washing with water, drying (MgSO4), filtration, evapn. to dryness, washing twice with pentane, elem. anal.;
DOI:10.1021/om020286b

Reference yield:

: [Au(C₆H₃(CH₂N(CH₃)2)2)]2

: 603-35-0
triphenylphosphine

: 474888-54-5
[Au(C₆H₃(CH₂NMe₂)2-2,6)(triphenylphosphine)]

Guidance literature:: In not given; (N2); using Schlenk techniques;
DOI:10.1021/om020286b

Reference yield: 96.0%

: 474888-54-5
[Au(C₆H₃(CH₂NMe₂)2-2,6)(triphenylphosphine)]

: 27199-13-9,14873-91-7,55528-77-3
bis(diethyl sulfide)palladium dichloride

: 14243-64-2
(triphenylphosphine)gold(I) chloride

: 82112-98-9
chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)

Guidance literature:: In toluene; byproducts: SEt2; (N2); using Schlenk techniques; addn. of PdCl2(SEt2)2 (1 equiv.) to soln. of Au(C6H3(CH2NMe2)2)(PPh3) (1 equiv.) in toluene; stirring for 30 minat room temp.; concn., addn. of Et2O, pptn., concn. of soln., addn. of pentane, pptn., elem. anal.;
DOI:10.1021/om020286b