chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)

Base Information

• Chemical Name: chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)
• CAS No.: 82112-98-9
• Molecular Formula: C₁₂H₁₉ClN₂Pd
• Molecular Weight: 333.169
• Mol file: 82112-98-9.mol

Synonyms:chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)

Chemical Property of chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)

There total 2 articles about chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

[Au(C6H3(CH2NMe2)2-2,6)(triphenylphosphine)] (474888-54-5) + bis(diethyl sulfide)palladium dichloride (27199-13-9,14873-91-7,55528-77-3) → (triphenylphosphine)gold(I) chloride (14243-64-2) + chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II) (82112-98-9)

Guidance literature:

In toluene; byproducts: SEt2; (N2); using Schlenk techniques; addn. of PdCl2(SEt2)2 (1 equiv.) to soln. of Au(C6H3(CH2NMe2)2)(PPh3) (1 equiv.) in toluene; stirring for 30 minat room temp.; concn., addn. of Et2O, pptn., concn. of soln., addn. of pentane, pptn., elem. anal.;

DOI:10.1021/om020286b

Reference yield:

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + rhodium{C6H3(CH2NMe2)2-o,o'}(1,5-cyclooctadiene) (115338-66-4) → di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II) (82112-98-9) + benzonitrile (100-47-0)

Guidance literature:

In dichloromethane; instant reaction; no sepn. of metal-contg. products (similar soly.);

DOI:10.1021/om00099a010

Reference yield: 98.0%

chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II) (82112-98-9) + silver benzoate (532-31-0) → benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II) (797057-61-5)

Guidance literature:

In acetone; under Ar; soln. of Pd complex in acetone added to Ag salt (molar ratio 1:1.1); stirred for 1 h in absence of light; filtered through Celite; filtrate concd. in vac.; pentane added; solid isolated; washed with pentane; dried in vac.; elem. anal.;

DOI:10.1021/om040061w

upstream raw materials:

bis(benzonitrile)palladium(II) dichloride

rhodium{C₆H₃(CH₂NMe₂)2-o,o'}(1,5-cyclooctadiene)

[Au(C₆H₃(CH₂NMe₂)2-2,6)(triphenylphosphine)]

bis(diethyl sulfide)palladium dichloride

Downstream raw materials:

μ-chlorobis[2,6-bis((dimethylamino)methyl)phenylpalladium(II)]tetrakis[4-(trimethylsilyl)phenyl]borate

benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)