Platinum, [2,6-bis[(dimethylamino)methyl]phenyl]chloro-

Base Information

• Chemical Name: Platinum, [2,6-bis[(dimethylamino)methyl]phenyl]chloro-
• CAS No.: 663164-11-2
• Molecular Formula: C12H19ClN2Pt
• Molecular Weight: 421.829
• Mol file: 663164-11-2.mol

Synonyms:

Chemical Property of Platinum, [2,6-bis[(dimethylamino)methyl]phenyl]chloro-

Chemical Property:

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Platinum, [2,6-bis[(dimethylamino)methyl]phenyl]chloro-

There total 1 articles about Platinum, [2,6-bis[(dimethylamino)methyl]phenyl]chloro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dichlorobis(diethyl sulfide)platinum (14873-92-8) + [Au(C6H3(CH2NMe2)2-2,6)(triphenylphosphine)] (474888-54-5) → (triphenylphosphine)gold(I) chloride (14243-64-2) + chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(II) (663164-11-2)

Guidance literature:

In benzene-d6; byproducts: SEt2; (N2); using Schlenk techniques; mixing of PtCl2(SEt2)2 and Au(C6H3(CH2NMe2)2)(PPh3) in 1:1 molar ratio in C6D6; reflux for 2 h; detected by NMR;

DOI:10.1021/om020286b

Reference yield: 98.0%

chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(II) (663164-11-2) + 1,3-bis(diphenylphosphinomethyl)benzene (89756-88-7) → (2,6-bis[methyl(diphenylphosphino)]phenyl)platinum chloride

Guidance literature:

In toluene; byproducts: m-C6H4(CH2NMe2)2; (N2); refluxed for 3 d; ppt. filtered off, filtrate evapd. (vac.), recrystd. (CH2Cl2, layering with pentane);

DOI:10.1021/ja001808m

Reference yield: 95.0%

chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(II) (663164-11-2) + silver benzoate (532-31-0) → benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(II) (797057-62-6)

Guidance literature:

In acetone; under Ar; soln. of Pt complex in acetone added to Ag salt (molar ratio 1:1); stirred overnight in absence of light; filtered through Celite; filtrate concd. in vac.; pentane added; solid isolated; washed with pentane; dried in vac.; elem. anal.;

DOI:10.1021/om040061w

upstream raw materials:

dichlorobis(diethyl sulfide)platinum

[Au(C₆H₃(CH₂NMe₂)2-2,6)(triphenylphosphine)]

Downstream raw materials:

{Pt(phenyl)(C₆H₃(CH₂NMe₂)2-2,6)}

4-tolyl(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(II)

C₆H₃(CH₂N(CH₃)2)2PtCCC₆H₄CN

C₆H₃(CH₂N(CH₃)2)2PtCCC₆H₃(CH₂N(CH₃)2)2