4-Decene-2,6-diol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-9-[(4-methoxyphenyl)methoxy]-3- methyl-10-[(2S,6R)-tetrahydro-6-(iodomethyl)-2H-pyran-2-yl]-, (2R,3R,4Z,6S,9S)-

Base Information

Chemical Name:4-Decene-2,6-diol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-9-[(4-methoxyphenyl)methoxy]-3- methyl-10-[(2S,6R)-tetrahydro-6-(iodomethyl)-2H-pyran-2-yl]-, (2R,3R,4Z,6S,9S)-
CAS No.:477953-56-3
Molecular Formula:C41H57IO6Si
Molecular Weight:800.89
Hs Code.:

4-Decene-2,6-diol,
1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-9-[(4-methoxyphenyl)methoxy]-3-
methyl-10-[(2S,6R)-tetrahydro-6-(iodomethyl)-2H-pyran-2-yl]-,
(2R,3R,4Z,6S,9S)-

Synonyms:

Suppliers and Price of 4-Decene-2,6-diol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-9-[(4-methoxyphenyl)methoxy]-3- methyl-10-[(2S,6R)-tetrahydro-6-(iodomethyl)-2H-pyran-2-yl]-, (2R,3R,4Z,6S,9S)-

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Chemical Property of 4-Decene-2,6-diol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-9-[(4-methoxyphenyl)methoxy]-3- methyl-10-[(2S,6R)-tetrahydro-6-(iodomethyl)-2H-pyran-2-yl]-, (2R,3R,4Z,6S,9S)-

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Technology Process of 4-Decene-2,6-diol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-9-[(4-methoxyphenyl)methoxy]-3- methyl-10-[(2S,6R)-tetrahydro-6-(iodomethyl)-2H-pyran-2-yl]-, (2R,3R,4Z,6S,9S)-

There total 6 articles about 4-Decene-2,6-diol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-9-[(4-methoxyphenyl)methoxy]-3- methyl-10-[(2S,6R)-tetrahydro-6-(iodomethyl)-2H-pyran-2-yl]-, (2R,3R,4Z,6S,9S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (Z)-(4R,5R,8S)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-8-[(S)-4-((2S,6R)-6-iodomethyl-tetrahydro-pyran-2-yl)-3-(4-methoxy-benzyloxy)-butyl]-2,2,5-trimethyl-5,8-dihydro-4H-[1,3,2]dioxasilocine

: 477953-56-3
(Z)-(2R,3R,6S,9S)-1-(tert-Butyl-diphenyl-silanyloxy)-10-((2S,6R)-6-iodomethyl-tetrahydro-pyran-2-yl)-9-(4-methoxy-benzyloxy)-3-methyl-dec-4-ene-2,6-diol

Guidance literature:: With trifluoroacetic acid; In tetrahydrofuran; methanol; at 20 ℃; for 24h;
DOI:10.1021/ol0268438

Reference yield:

: 477953-48-3
(2R,3R)-3-Methyl-1-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-4-penten-2-ol

: 477953-56-3
(Z)-(2R,3R,6S,9S)-1-(tert-Butyl-diphenyl-silanyloxy)-10-((2S,6R)-6-iodomethyl-tetrahydro-pyran-2-yl)-9-(4-methoxy-benzyloxy)-3-methyl-dec-4-ene-2,6-diol

Guidance literature:: Multi-step reaction with 4 steps

1.1: BuLi / tetrahydrofuran; various solvent(s) / 0.17 h / -78 °C

1.2: tetrahydrofuran / -78 - 20 °C

2.1: imidazole / tetrahydrofuran / 16 h / 20 °C

3.1: Schrock's molybdenum catalyst / benzene / 24 h / 20 °C

4.1: TFA / tetrahydrofuran; methanol / 24 h / 20 °C

With 1H-imidazole; n-butyllithium; trifluoroacetic acid; bis[1,1-di(trifluoromethyl)ethoxy][(2,6-diisopropylphenyl)imino](2-methyl-2-phenylpropylidene)molybdenum; In tetrahydrofuran; methanol; benzene;
DOI:10.1021/ol0268438

Reference yield:

: C₂₄H₃₅ClO₂Si₂

: 477953-56-3
(Z)-(2R,3R,6S,9S)-1-(tert-Butyl-diphenyl-silanyloxy)-10-((2S,6R)-6-iodomethyl-tetrahydro-pyran-2-yl)-9-(4-methoxy-benzyloxy)-3-methyl-dec-4-ene-2,6-diol

Guidance literature:: Multi-step reaction with 3 steps

1: imidazole / tetrahydrofuran / 16 h / 20 °C

2: Schrock's molybdenum catalyst / benzene / 24 h / 20 °C

3: TFA / tetrahydrofuran; methanol / 24 h / 20 °C

With 1H-imidazole; trifluoroacetic acid; bis[1,1-di(trifluoromethyl)ethoxy][(2,6-diisopropylphenyl)imino](2-methyl-2-phenylpropylidene)molybdenum; In tetrahydrofuran; methanol; benzene;
DOI:10.1021/ol0268438