Methanimidamide, N,N'-bis(3-bromophenyl)-

Base Information

• Chemical Name: Methanimidamide, N,N'-bis(3-bromophenyl)-
• CAS No.: 49755-06-8
• Molecular Formula: C13H10Br2N2
• Molecular Weight: 354.044
• Mol file: 49755-06-8.mol

Synonyms:

Chemical Property of Methanimidamide, N,N'-bis(3-bromophenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methanimidamide, N,N'-bis(3-bromophenyl)-

There total 2 articles about Methanimidamide, N,N'-bis(3-bromophenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.3%

acetic acid (64-19-7,77671-22-8) + m-Bromoaniline (591-19-5) → N,N'-bis-(3-bromo-phenyl)-formamidine (49755-06-8)

Guidance literature:

With orthoformic acid triethyl ester; at 140 ℃; for 24h;

DOI:10.1021/acs.joc.8b00151

Reference yield: 78.0%

orthoformic acid triethyl ester (122-51-0) + m-Bromoaniline (591-19-5) → N,N'-bis-(3-bromo-phenyl)-formamidine (49755-06-8)

Guidance literature:

With carbon dots coated magnetic Fe₃O₄ nanoparticles; In neat (no solvent); at 100 ℃; for 0.833333h; Green chemistry;

DOI:10.1002/aoc.6387

Reference yield: 96.1%

1,4-dibromo-butane (110-52-1) + N,N'-bis-(3-bromo-phenyl)-formamidine (49755-06-8) → C17H18Br2N2O

Guidance literature:

With potassium carbonate; In acetonitrile; at 100 ℃;

DOI:10.1021/acs.joc.8b00151

upstream raw materials:

orthoformic acid triethyl ester

m-Bromoaniline

acetic acid

Downstream raw materials:

2-acetyl-3-(3-bromo-anilino)-acrylic acid-(3-bromo-anilide)

m-Bromoaniline

1-(3-Bromo-phenyl)-1-{[(E)-3-bromo-phenylimino]-methyl}-3-methyl-urea

N¹,N³-bis(3-bromophenyl)propane-1,3-diamine

Refernces

• 1、 Bulut, Safak,Queen, Wendy L.. "Catalyst-Free Synthesis of Aryl Diamines via a Three-Step Reaction Process". . p. 3806 - 3818. Retrieved 2018/04/14.