3-Buten-2-one, 1-[(R)-(4-methylphenyl)sulfinyl]-

Base Information

Chemical Name:3-Buten-2-one, 1-[(R)-(4-methylphenyl)sulfinyl]-
CAS No.:503565-88-6
Molecular Formula:C11H12O2S
Molecular Weight:208.281
Hs Code.:
DSSTox Substance ID:DTXSID30463361
Wikidata:Q82288222
Mol file:503565-88-6.mol

Synonyms:3-Buten-2-one, 1-[(R)-(4-methylphenyl)sulfinyl]-;503565-88-6;DTXSID30463361

Suppliers and Price of 3-Buten-2-one, 1-[(R)-(4-methylphenyl)sulfinyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-Buten-2-one, 1-[(R)-(4-methylphenyl)sulfinyl]-

Chemical Property:

XLogP3:1.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:208.05580079
Heavy Atom Count:14
Complexity:240

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=C(C=C1)S(=O)CC(=O)C=C
Isomeric SMILES:CC1=CC=C(C=C1)[S@](=O)CC(=O)C=C

Technology Process of 3-Buten-2-one, 1-[(R)-(4-methylphenyl)sulfinyl]-

There total 1 articles about 3-Buten-2-one, 1-[(R)-(4-methylphenyl)sulfinyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 1519-39-7
(R)-methyl p-tolyl sulfoxide

: 40736-25-2
1-acryloyl imidazole

: 503565-88-6
(1R)-(4-methylphenylsulfinyl)-3-buten-2-one

Guidance literature:: (R)-methyl p-tolyl sulfoxide; With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -30 ℃; for 0.333333h;

1-acryloyl imidazole; In tetrahydrofuran; hexane; at -15 ℃; for 0.333333h;
DOI:10.1016/S0957-4166(02)00782-6

Reference yield: 93.0%

: 503565-88-6
(1R)-(4-methylphenylsulfinyl)-3-buten-2-one

: 73766-46-8
(1R)-(4-methylphenylsulfinyl)-(2S)-3-buten-2-ol

Guidance literature:: With diisobutylaluminium hydride; In tetrahydrofuran; toluene; at -78 ℃; for 2h;
DOI:10.1016/S0957-4166(02)00782-6

Reference yield:

: 503565-88-6
(1R)-(4-methylphenylsulfinyl)-3-buten-2-one

: 252032-39-6
1-bromo-(4S)-(4-methylphenylsulfinyl)-(2S,3S)-butane-2,3-diol

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / DIBAL / tetrahydrofuran; toluene / 2 h / -78 °C

2: 81 percent / NBS; H₂O / toluene / 0.5 h / 20 °C

With N-Bromosuccinimide; water; diisobutylaluminium hydride; In tetrahydrofuran; toluene;
DOI:10.1016/S0957-4166(02)00782-6