1H-Phosphole, 3,4-dimethyl-2-phenyl-1-(trimethylstannyl)-

Base Information

Chemical Name:1H-Phosphole, 3,4-dimethyl-2-phenyl-1-(trimethylstannyl)-
CAS No.:515877-62-0
Molecular Formula:C15H21PSn
Molecular Weight:351.015
Hs Code.:

Synonyms:

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Chemical Property of 1H-Phosphole, 3,4-dimethyl-2-phenyl-1-(trimethylstannyl)-

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Technology Process of 1H-Phosphole, 3,4-dimethyl-2-phenyl-1-(trimethylstannyl)-

There total 1 articles about 1H-Phosphole, 3,4-dimethyl-2-phenyl-1-(trimethylstannyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1066-45-1
trimethyltin(IV)chloride

: 30540-36-4
3,4-dimethyl-1-phenylphosphole

: 515877-62-0
1-(trimethylstannyl)-3,4-dimethyl-2-phenylphosphole

Guidance literature:: With KOC(CH₃)3; In tetrahydrofuran; phosphole, KOC(CH3)3 and THF heated at 140 °C for 20 h in sealed tube, soln. cooled to room temp., volatiles removed (vac.), THF added and removed (vac.), solid dissolved in THF, soln. of (CH3)3SnCl added, reaction stirred for 15 min; soln. evapd. (vac.), residue extd. (hexane), filtered, concd.;
DOI:10.1039/b208945a

Reference yield: 82.0%

: TiCl₄(THF)₂

: 515877-62-0
1-(trimethylstannyl)-3,4-dimethyl-2-phenylphosphole

: 880152-10-3
(η5-3,4-dimethyl-2-phenylphospholyl)titanium trichloride

Guidance literature:: In toluene; pentane; (Ar); std. Schlenk technique; soln. of phosphole in pentane was rapidly added to soln. of Ti compd. in toluene at 0°C; soln. was warmed to room temp. and stirred overnight; volatiles evapd. (vac.); extd. (toluene); solvent removed (vac.);
DOI:10.1021/om050357h

Reference yield: 75.0%

: titanium(IV) chloride tetrahydrofuran

: 515877-62-0
1-(trimethylstannyl)-3,4-dimethyl-2-phenylphosphole

: 516493-57-5,515877-60-8
(η5-C4Me2(Ph)HP)2TiCl2

Guidance literature:: In hexane; dichloromethane; soln. of stannylphosphole in C6H14 added rapidly to soln. of TiCl4*2THF in CH2Cl2 at room temp., mixt. stirred for 4 h; soln. concd., washed (C6H14), dried (vac.);
DOI:10.1039/b208945a