Lithium, [2-(methylthio)phenyl]-

Base Information

Chemical Name:Lithium, [2-(methylthio)phenyl]-
CAS No.:51894-94-1
Molecular Formula:C7H7LiS
Molecular Weight:130.14
Hs Code.:
DSSTox Substance ID:DTXSID80472721
Mol file:51894-94-1.mol

Synonyms:Lithium, [2-(methylthio)phenyl]-;lithiot hioanisole;51894-94-1;DTXSID80472721

Suppliers and Price of Lithium, [2-(methylthio)phenyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Lithium, [2-(methylthio)phenyl]-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:130.04284983
Heavy Atom Count:9
Complexity:156

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:[Li+].CSC1=CC=CC=[C-]1

Technology Process of Lithium, [2-(methylthio)phenyl]-

There total 1 articles about Lithium, [2-(methylthio)phenyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 19614-16-5
2-bromo-1-(methylsulfanyl)benzene

: 51894-94-1
o-lithiothioanisole

Guidance literature:: With n-butyllithium; In diethyl ether; hexane; for 1.5h;
DOI:10.1246/bcsj.61.1195

Reference yield: 85.0%

: 107-03-9
1-thiopropane

: 199620-14-9,13007-92-6
chromium⁽⁰⁾ hexacarbonyl

: 110-60-1
1,4-diaminobutane

: 51894-94-1
o-lithiothioanisole

: (CO)5CrC(SC₃H₇)(C₆H₄SCH₃)

Guidance literature:: With acetyl chloride; In diethyl ether; byproducts: CH3COOH; (N2); 0°C; after 1 h evapn. of solvent; addn. of CH2Cl2; -40°C; addn. of TMEDA and acetyl chloride; after 30 min. addn. of n-C3H7SH; stirring 30 min.; warmed to room temp. in 3 h; filtration ( silica gel ); chromy. ( silica gel; ether/petroleum ether 1/5 ) at -15°C;

Reference yield: 69.0%

: 98-02-2,175236-33-6
2-thiolomethyl-furan

: 199620-14-9,13007-92-6
chromium⁽⁰⁾ hexacarbonyl

: 110-60-1
1,4-diaminobutane

: 51894-94-1
o-lithiothioanisole

: (CO)5CrC(SCH₂C₄H₃O)(C₆H₄SCH₃)

Guidance literature:: With acetyl chloride; In diethyl ether; byproducts: CH3COOH; (N2); 0°C; after 1 h evapn. of solvent; addn. of CH2Cl2; -40°C; addn. of TMEDA and acetyl chloride; after 30 min. addn. of C4H3OCH2SH; stirring 30 min.; warmed to room temp. in 3 h; filtration (silica gel); chromy. (silica gel; ether/petroleum ether 1/5) at -15°C;