Benzene, 1-[(4-methoxyphenyl)methyl]-3-methyl-

Base Information

Chemical Name:Benzene, 1-[(4-methoxyphenyl)methyl]-3-methyl-
CAS No.:53039-51-3
Molecular Formula:C15H16O
Molecular Weight:212.291
Hs Code.:
DSSTox Substance ID:DTXSID10481124
Nikkaji Number:J2.159.459H
Wikidata:Q82316361

Synonyms:53039-51-3;Benzene, 1-[(4-methoxyphenyl)methyl]-3-methyl-;1-methoxy-4-(3-methylbenzyl)benzene;SCHEMBL20418385;DTXSID10481124

Suppliers and Price of Benzene, 1-[(4-methoxyphenyl)methyl]-3-methyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzene, 1-[(4-methoxyphenyl)methyl]-3-methyl-

Chemical Property:

XLogP3:4.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:212.120115130
Heavy Atom Count:16
Complexity:194

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=CC=C1)CC2=CC=C(C=C2)OC

Technology Process of Benzene, 1-[(4-methoxyphenyl)methyl]-3-methyl-

There total 17 articles about Benzene, 1-[(4-methoxyphenyl)methyl]-3-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 14503-41-4
m-methylbenzyl tosylate

: 5720-07-0
4-methoxyphenylboronic acid

: 53039-51-3
1-(4-methoxybenzyl)-3-methylbenzene

Guidance literature:: With NHC-Pd(II)-Im; sodium hydroxide; In tetrahydrofuran; at 100 ℃; for 12h; Inert atmosphere; Sealed tube;
DOI:10.1039/c4ob02675f

Reference yield: 96.0%

: 5720-07-0
4-methoxyphenylboronic acid

: N,N,N-trimethyl-1-(m-tolyl)methanaminium iodide

: 53039-51-3
1-(4-methoxybenzyl)-3-methylbenzene

Guidance literature:: With potassium phosphate; (NC₅H₃(N₂C₇H₄(CH₂)3CH₃)2)NiBr⁽¹⁺⁾*Br^(1-)=Ni(NC₅H₃(N₂C₇H₄(CH₂)3CH₃)2)Br₂; triphenylphosphine; In 1,4-dioxane; at 80 ℃; for 24h; Schlenk technique;
DOI:10.1016/j.cclet.2016.09.006

Reference yield: 94.0%

: 104-92-7
1-bromo-4-methoxy-benzene

: 591-17-3
meta-bromotoluene

: 78782-17-9
4,4,5,5-tetramethyl-2-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-1,3,2-dioxaborolane

: 53039-51-3
1-(4-methoxybenzyl)-3-methylbenzene

Guidance literature:: 1-bromo-4-methoxy-benzene; 4,4,5,5-tetramethyl-2-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-1,3,2-dioxaborolane; With bis(tri-t-butylphosphine)palladium⁽⁰⁾; potassium hydroxide; In 1,4-dioxane; water; at 20 ℃; for 3h; Inert atmosphere;

meta-bromotoluene; With potassium hydroxide; In 1,4-dioxane; water; at 60 ℃; for 16h; Inert atmosphere;
DOI:10.1021/jo3015165