Phosphinic amide, diphenyl-N-triphenylphosphoranylidene-

Base Information

• Chemical Name: Phosphinic amide, diphenyl-N-triphenylphosphoranylidene-
• CAS No.: 24082-36-8
• Molecular Formula: C30H25 N P2
• Molecular Weight: 461.483
• DSSTox Substance ID: DTXSID20178811
• Wikidata: Q83049292
• Mol file: 24082-36-8.mol

Synonyms:24082-36-8;Phosphinic amide, diphenyl-N-triphenylphosphoranylidene-;diphenylphosphanylimino(triphenyl)-lambda5-phosphane;SCHEMBL4883137;DTXSID20178811

Chemical Property of Phosphinic amide, diphenyl-N-triphenylphosphoranylidene-

Chemical Property:

• Boiling Point: 601.3±38.0 °C(Predicted)
• PSA: 49.05000
• LogP: 6.09320
• XLogP3: 7.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 6
• Exact Mass: 461.14622380
• Heavy Atom Count: 33
• Complexity: 545

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)N=P(C3=CC=CC=C3)(C4=CC=CC=C4)C5=CC=CC=C5

Technology Process of Phosphinic amide, diphenyl-N-triphenylphosphoranylidene-

There total 5 articles about Phosphinic amide, diphenyl-N-triphenylphosphoranylidene- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

amino(triphenyl)phosphonium chloride (15729-44-9) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → N-diphenylphosphino-P,P,P-triphenylphosphinimide (24082-36-8)

Guidance literature:

amino(triphenyl)phosphonium chloride; With n-butyllithium; In tetrahydrofuran; hexane; at -20 ℃; for 0.5h;

chloro-diphenylphosphine; at -20 - 25 ℃; Further stages.;

DOI:10.1039/b603677e

Reference yield:

bis(triphenylphosphine)iminium chloride (21050-13-5) → imino(triphenyl)phosphorane (2240-47-3) + N-diphenylphosphino-P,P,P-triphenylphosphinimide (24082-36-8)

Guidance literature:

Multi-step reaction with 3 steps

1: water / 1 h / 0 °C / Inert atmosphere; Schlenk technique

2: methanol / 1 h / 20 °C / Inert atmosphere; Schlenk technique

3: propiononitrile

With propiononitrile; In methanol; water;

DOI:10.1039/c3dt52617h

Reference yield:

bis(triphenyl-λ5-phosphanylidene)ammonium fluoride (38011-30-2) → imino(triphenyl)phosphorane (2240-47-3) + N-diphenylphosphino-P,P,P-triphenylphosphinimide (24082-36-8)

Guidance literature:

With propiononitrile; Solvent;

DOI:10.1039/c3dt52617h

upstream raw materials:

amino(triphenyl)phosphonium chloride

chloro-diphenylphosphine

bis(triphenylphosphine)iminium chloride

bis(triphenyl-λ⁵-phosphanylidene)ammonium fluoride

Downstream raw materials:

[AuCl(N-diphenylphosphinotriphenylphosphinimine)]

[Au(N-diphenylphosphinotriphenylphosphinimine)2]Cl