15729-44-9

Basic information

• Product Name: AMINO(TRIPHENYL)PHOSPHONIUM CHLORIDE
• Synonyms: AMINO(TRIPHENYL)PHOSPHONIUM CHLORIDE
• CAS NO: 15729-44-9
• Molecular Formula: C₁₈H₁₇NP*Cl
• Molecular Weight: 313.76
• Mol File: 15729-44-9.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• CAS DataBase Reference: AMINO(TRIPHENYL)PHOSPHONIUM CHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: AMINO(TRIPHENYL)PHOSPHONIUM CHLORIDE(15729-44-9)
• EPA Substance Registry System: AMINO(TRIPHENYL)PHOSPHONIUM CHLORIDE(15729-44-9)

Safety Data

• Hazardous Substances Data: 15729-44-9(Hazardous Substances Data)

Upstream product

• 603-35-0 triphenylphosphine 
• 15318-33-9 trans-carbonyl(chloro)bis(triphenylphosphine)rhodium(I) 
• 12190-75-9 chloroamine 
• 33082-06-3 (triphenylphosphoranediyl)aminocyclotrithiatriazene 
• 1034-39-5 dibromotriphenylphosphorane 

Downstream Products

• 59532-99-9 (dichloro-morpholin-4-yl-methyl)-(triphenyl-λ⁵-phosphanylidene)-amine 
• 2240-47-3 imino(triphenyl)phosphorane 
• 21050-13-5 bis(triphenylphosphine)iminium chloride 
• 1195953-56-0 Br^(1-)*C₂₈H₂₆NP₂⁽¹⁺⁾ 
• 1195953-57-1 Br^(1-)*C₂₄H₂₇N₄P₂⁽¹⁺⁾ 
• 24082-36-8 N-diphenylphosphino-P,P,P-triphenylphosphinimide 
• 910048-41-8 C₆₆H₅₅N₃P₅⁽¹⁺⁾*Cl^(1-) 
• 910048-43-0 C₅₄H₄₅Cl₂N₃P₄ 
• 17986-01-5 N-methyl-P,P,P-triphenylphosphine imide 
• 17436-52-1 benzoyliminotriphenylphosphorane 
• 126864-14-0 C₂₉H₃₁NP⁽¹⁺⁾*I^(1-) 

Relevant articles and documents

13C and 31P NMR Studies of Some Aminophosphonium Chlorides

The multinuclear NMR spectral data for an homologous series of tertiary phosphines R(3-n)P(NMe2)(n), aminophosphonium ions, (+), and phosphonium ions, (+), where R=Me, Et, (n)-Pr and Ph, R' and/or R''=H, Me and n=0 and 1 are reported and discussed.Quaternization by alkylation or alkylation or chloramination causes an increase in the 31P chemical shift (ΔδP is positive), a decrease in the 13C chemical shift (ΔδC is negative) for all carbons, an increase in the magnitudes of 1J(PC), 3J(PC), 3J(PNCH) and 2J(PCH) and a decrease in the magnitude of 2J(PC).Substitution of a Me2N group for an alkyl or aryl group produces an increase in the 31P chemical shift and in the magnitude of 1J(PC). α- and β-deshielding and γ-shielding effects are noted in the 13C NMR spectra and β-deshielding and γ-shielding effects are noted in the 31P NMR spectra with substitution on the phosphorus and nitrogen atoms. - Key words: 13C NMR, 31P NMR, Tertiary phosphines, Aminophosphonium ions, Phosphonium ions

An Unaspected Synthesis of Tripheriylphosphazenium Chloride, [(C6H5)3PNH2]+Cl -, and a Redetermination of its Crystal Structure

Triphenylphosphazenium chloride has been prepared by the reaction of triphenylphosphine with trimethylsilylazide in impure, wet dichloromethane. Yields arc improved as stoichiometric quantities of water are added. Colourless crystals are obtained by recry

A new and convenient method for the synthesis of strong non-ionic bases

Various strong non-ionic phosphazene bases were obtained by a new, efficient and very simple method involving the lithium phosphonium azayldiide Ph3P=NLi (2) as a precursor. The Royal Society of Chemistry 2006.