4-Allyloxybiphenyl

Base Information

• Chemical Name: 4-Allyloxybiphenyl
• CAS No.: 20281-44-1
• Molecular Formula: C15H14O
• Molecular Weight: 210.276
• NSC Number: 86618
• DSSTox Substance ID: DTXSID60942412
• Nikkaji Number: J668.593E
• Wikidata: Q82919419
• Mol file: 20281-44-1.mol

Synonyms:20281-44-1;4-allyloxybiphenyl;NSC86618;4-allyloxybi-phenyl;4-Allyloxy-biphenyl;NCIOpen2_004916;SCHEMBL472119;DTXSID60942412;FSLXCIJOWQAYPN-UHFFFAOYSA-N;NSC-86618;4-[(Prop-2-en-1-yl)oxy]-1,1'-biphenyl

Chemical Property of 4-Allyloxybiphenyl

Chemical Property:

• Vapor Pressure: 0.000204mmHg at 25°C
• Boiling Point: 337.6°Cat760mmHg
• Flash Point: 133.6°C
• Density: 1.016g/cm³
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 210.104465066
• Heavy Atom Count: 16
• Complexity: 198

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCOC1=CC=C(C=C1)C2=CC=CC=C2

Technology Process of 4-Allyloxybiphenyl

There total 5 articles about 4-Allyloxybiphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

4-Phenylphenol (92-69-3) + allyl bromide (106-95-6) → 4-allyloxy-biphenyl (20281-44-1)

Guidance literature:

With caesium carbonate; In N,N-dimethyl-formamide; at 23 ℃; for 1h;

DOI:10.1080/00397919908086606

Reference yield:

5-(Biphenyl-4-yloxy)-1-phenyl-pentan-1-one → 4-allyloxy-biphenyl (20281-44-1) + acetophenone (98-86-2)

Guidance literature:

In cyclohexane; at 20 ℃; Kinetics; Quantum yield; UV-irradiation;

DOI:10.1021/ja990224l

Reference yield:

4-bromo-phenol (106-41-2) → 4-allyloxy-biphenyl (20281-44-1)

Guidance literature:

Multi-step reaction with 3 steps

1.1: potassium carbonate / acetone / 5 h / Reflux

2.1: isopropyl alcohol / 0.17 h / 20 °C

2.2: 18 h / 90 °C / Inert atmosphere

3.1: potassium carbonate / acetone / 5 h / Reflux

With potassium carbonate; In isopropyl alcohol; acetone; 2.1: Suzuki coupling / 2.2: Suzuki coupling;

DOI:10.3390/molecules17078091

upstream raw materials:

4-Phenylphenol

allyl bromide

sodium 4-phenylphenoxide

4-bromo-phenol

Downstream raw materials:

3-allyl-(1,1’-biphenyl)-4-ol

4-Phenylphenol

triphenyl[3-(4-biphenyloxy)propyl]tin

(S)-1-phenyl-2-(5-phenyl-2,3-dihydrobenzofuran-2-yl)ethanone