triphosphane

Base Information

• Chemical Name: triphosphane
• CAS No.: 13597-70-1
• Molecular Formula: H5P3
• Molecular Weight: 97.961
• DSSTox Substance ID: DTXSID80159606
• Nikkaji Number: J594.990D
• Wikipedia: Triphosphane
• Wikidata: Q1107689
• Mol file: 13597-70-1.mol

Synonyms:Triphosphine;triphosphane;13597-70-1;CHEBI:35893;DTXSID80159606;Q1107689

Chemical Property of triphosphane

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• XLogP3: -0.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 97.96041115
• Heavy Atom Count: 3
• Complexity: 0

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: PPP

Technology Process of triphosphane

There total 2 articles about triphosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diphosphane (12185-09-0) → triphosphine (13597-70-1) + phosphan (7803-51-2)

Guidance literature:

In not given; byproducts: phosphorus hydrides; Irradiation (UV/VIS); dismutation of P2H4 by irradiation forming PH3, P3H5 and phosphorus hydrides;; observed by Raman spectroscopy;;

Reference yield:

diphosphane(4) + dihydrogen peroxide (7722-84-1) → triphosphine (13597-70-1) + phosphinophosphinic acid (73416-78-1) + bis(phosphino)phospninic acid (169905-45-7) + phosphan (7803-51-2)

Guidance literature:

In water; -78°C, then -40°C; followed by NMR;

upstream raw materials:

diphosphane

dihydrogen peroxide