Trifluoromethyl hypofluorite

Base Information

• Chemical Name: Trifluoromethyl hypofluorite
• CAS No.: 373-91-1
• Molecular Formula: CF4 O
• Molecular Weight: 104.004
• Hs Code.: 2920909090
• European Community (EC) Number: 206-772-7
• DSSTox Substance ID: DTXSID4073174
• Nikkaji Number: J213.568J
• Wikipedia: Trifluoromethyl_hypofluorite
• Wikidata: Q7841508
• Mol file: 373-91-1.mol

Synonyms:trifluoromethyl hypofluoride;trifluoromethyl hypofluorite

Chemical Property of Trifluoromethyl hypofluorite

Chemical Property:

• Vapor Pressure: 9460mmHg at 25°C
• Melting Point: -213°C
• Boiling Point: -95°C
• Flash Point: °C
• PSA: 9.23000
• Density: 1.419g/cm³
• LogP: 1.40730
• XLogP3: 1.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 103.98852727
• Heavy Atom Count: 6
• Complexity: 37.3

Purity/Quality:

99%, ^*data from raw suppliers

TRIFLUOROMETHYLHYPOFLUORITE 98.00% ^*data from reagent suppliers

Safty Information:

• Statements: 8-23-34
• Safety Statements: 17-26-38-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(OF)(F)(F)F

Technology Process of Trifluoromethyl hypofluorite

There total 27 articles about Trifluoromethyl hypofluorite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

Carbonyl fluoride (353-50-4) → hypofluorous acid trifluoromethyl ester (373-91-1)

Guidance literature:

copper; cesium fluoride; at 100 ℃;

Reference yield: 97.0%

Carbonyl fluoride (353-50-4) + fluorine (7782-41-4) → hypofluorous acid trifluoromethyl ester (373-91-1)

Guidance literature:

rubidium fluoride; equimolar amt. of educts, steel vessel, -78°C, yield: 97 mol-%;

DOI:10.1021/ja00971a058

Reference yield: 95.0%

Carbonyl fluoride (353-50-4) + fluorine (7782-41-4) → hypofluorous acid trifluoromethyl ester (373-91-1) + bis(trifluoromethyl)peroxide (927-84-4)

Guidance literature:

yttrium(III) fluoride; 150°C, 10 h; Kinetics;

upstream raw materials:

methanol

Carbonyl fluoride

Bromotrifluoromethane

trifluoroketone

Downstream raw materials:

bis(trifluoromethyl)peroxide

carbon tetrafluoride

Difluoromethane

trifluoromethan

Refernces

• 1、 Zhang, Fumin,Francisco, J. S.,Steinfeld, J. I.. "Multiple Infrared Photon Dissociation and Kinetics of CF3O Radicals". . p. 2402 - 2406. Retrieved 1982.
• 2、 Marantz. "". . p. 4380. Retrieved 1965.
• 3、 -. "Method of synthesis and purification for trifluoromethyle hypofluorite". Paragraph 0080-0087. . Retrieved 2017/09/21.
• 4、 -. "Process for preparing fluorohalogenethers". Page/Page column 4. . Retrieved 2008/06/13.