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927-84-4

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927-84-4 Usage

General Description

Bis(trifluoromethyl)peroxide is a colorless, potentially explosive chemical compound with the formula CF3OOOCF3. It is a peroxide, meaning it contains an oxygen-oxygen single bond. BIS(TRIFLUOROMETHYL)PEROXIDE is highly reactive and must be handled with extreme care due to its explosive nature. It is primarily used as a radical initiator in various chemical reactions, particularly in the synthesis of high-performance polymers and other organic compounds. Due to its extreme reactivity, bis(trifluoromethyl)peroxide must be stored and handled in a secure and controlled manner to prevent accidental explosions. It is essential to follow strict safety protocols when working with this compound to avoid potential hazards.

Check Digit Verification of cas no

The CAS Registry Mumber 927-84-4 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 9,2 and 7 respectively; the second part has 2 digits, 8 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 927-84:
(5*9)+(4*2)+(3*7)+(2*8)+(1*4)=94
94 % 10 = 4
So 927-84-4 is a valid CAS Registry Number.
InChI:InChI=1/C2F6O2/c3-1(4,5)9-10-2(6,7)8

927-84-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name BIS(TRIFLUOROMETHYL)PEROXIDE

1.2 Other means of identification

Product number -
Other names trifluoromethyl peroxide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:927-84-4 SDS

927-84-4Relevant articles and documents

Anderson,Fox

, p. 4313 (1967)

Radical C?H Trifluoromethoxylation of (Hetero)arenes with Bis(trifluoromethyl)peroxide

Dix, Stefan,Golz, Paul,Schmid, Jonas R.,Riedel, Sebastian,Hopkinson, Matthew N.

supporting information, p. 11554 - 11558 (2021/07/09)

Trifluoromethoxylated (hetero)arenes are of great interest for several disciplines, especially in agro- and medicinal chemistry. Radical C?H trifluoromethoxylation of (hetero)arenes represents an attractive approach to prepare such compounds, but the high cost and low atom economy of existing .OCF3 radical sources make them unsuitable for the large-scale synthesis of trifluoromethoxylated building blocks. Herein, we introduce bis(trifluoromethyl)peroxide (BTMP, CF3OOCF3) as a practical and efficient trifluoromethoxylating reagent that is easily accessible from inexpensive bulk chemicals. Using either visible light photoredox or TEMPO catalysis, trifluoromethoxylated arenes could be prepared in good yields under mild conditions directly from unactivated aromatics. Moreover, TEMPO catalysis allowed for the one-step synthesis of valuable pyridine derivatives, which have been previously prepared via multi-step approaches.

Synthesis and properties of trifluoromethoxyl fluoroformyl anhydride, CF3OC(O)OC(O)F

Manetti, Martín M.,Argüello, Gustavo A.,Paci, Maxi A. Burgos

experimental part, p. 16 - 20 (2012/10/08)

In the present work the synthesis of the trifluoromethoxyl fluoroformyl anhydride is presented for the first time. Two strategies were employed to obtain CF3OC(O)OC(O)F: the thermal decomposition of CF 3OC(O)OOOC(O)F in excess of CO, and the reaction between CF 3OC(O)OOC(O)F, FC(O)OOC(O)F and CO. A mechanism was proposed taking into account reaction rates and thermal stability of the intermediates. DFT calculations at B3LYP/6-311+G* level were used to explore the conformational space of this molecule and the relative populations of conformers at room temperature, and to simulate the experimental vibrational spectrum. This molecule completes the family of the asymmetric oxygen bonded acyl compounds CF3OC(O)OxC(O)F with x = 1-3.

The use of perfluoroalkyl hypofluorites for an efficient synthesis of perfluorinated ethers characterized by low Ostwald coefficient

Navarrini, Walter,Venturini, Francesco,Sansotera, Maurizio,Ursini, Maurizio,Metrangolo, Pierangelo,Resnati, Giuseppe,Galimberti, Marco,Barchiesi, Emma,Dardani, Patrizia

, p. 680 - 685 (2008/12/22)

In the reaction between perfluoroolefins and perfluoroalkylhypofluorites the existence of two different free radical reaction mechanisms is demonstrated by the presence of characteristic byproducts. These kinetic schemes can be experimentally controlled b

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