Palladium, diamminedichloro-, cis-

Base Information

• Chemical Name: Palladium, diamminedichloro-, cis-
• CAS No.: 14323-43-4
• Molecular Formula: Cl₂H₆N₂Pd
• Molecular Weight: 211.387
• Hs Code.: 2843900090
• Mol file: 14323-43-4.mol

Synonyms:chloropalladosamine

Chemical Property of Palladium, diamminedichloro-, cis-

Chemical Property:

• Vapor Pressure: 0Pa at 20℃
• PSA: 6.48000
• Density: 2.5g/mLat 25°C(lit.)
• LogP: 2.02680
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility.: Slightly soluble in water. Soluble in NH₄OH. Insoluble in chloroform, acetone
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 209.89428
• Heavy Atom Count: 5
• Complexity: 0

Purity/Quality:

99.9% ^*data from raw suppliers

trans-Dichlorodiamminepalladium(II) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 23/24/25-36/37/38
• Safety Statements: 22-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: N.N.[Cl-].[Cl-].[Pd+2]
• Use Description: Dichlorodiamminepalladium, often referred to as palladium dichloride or PdCl2(NH3)2, has important applications in various fields. In the field of catalysis, it serves as a crucial catalyst in organic synthesis reactions, enabling the formation of carbon-carbon and carbon-heteroatom bonds. This catalytic role is fundamental in the production of pharmaceuticals, fine chemicals, and agrochemicals. In the field of materials science, palladium dichloride is used to prepare palladium nanoparticles, which find applications in catalysis, sensors, and as components in fuel cells for clean energy production. Moreover, in the field of analytical chemistry, it plays a role in chemical analysis, serving as a reagent for the determination of substances like sulfur and selenium. Its versatility as a catalyst, nanoparticle precursor, and analytical reagent underscores its significance in advancing multiple scientific disciplines and industries, contributing to the development of new materials and the synthesis of complex organic molecules.

Technology Process of Palladium, diamminedichloro-, cis-

There total 54 articles about Palladium, diamminedichloro-, cis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

ammonium tetrachloropalladate(II) → trans-diamminedichloride palladium(II) (13782-33-7,14323-43-4,15684-18-1)

Guidance literature:

In neat (no solvent); byproducts: HCl; isothermal decompn. at 216°C; elem. anal.;

Reference yield: 96.0%

ammonia (7664-41-7) + palladium dichloride → diamminedichloropalladium(II) (14323-43-4,15684-18-1,13782-33-7)

Guidance literature:

In hydrogenchloride; PdCl2 was dissolved in 0.2 M HCl, 25 % aq. NH3 was added at 50 °C, stirring for 2 h; soln. was ice-cooled, concd. HCl was added, solid was filtered, washed several times with water (ice-cooled), dried;

Reference yield: 90.0%

chloroauric acid + tetraamminepalladium(II) nitrate → diamminedichloropalladium(II) (14323-43-4,15684-18-1,13782-33-7) + tetraamminepalladium(II) tetrachloroaurate (III)

Guidance literature:

In water; HAuCl4 added to satd. aq. soln. of Pd(NH3)4(NO3)2; ppt. filtered off (vac.); washed (min. amt. of H2O, EtOH); dried (air); elem. anal.;

DOI:10.1134/S0036023607030138

upstream raw materials:

tetramminepalladium(II) chloride

hydrogenchloride

ammonia

palladium

Downstream raw materials:

palladium sulfide

palladium

tetrachloro diammine palladium (IV)

tetramminepalladium(II) chloride

Refernces

• 1、 Mitkina, Tatiana V.,Naumov, Dmitriy Yu.,Gerasko, Olga A.,Fedin, Vladimir P.. "Crystal structure and chemical oxidation of the palladium(II) cyclam complex within the cavity of cucurbit[8]uril". . p. 4387 - 4391. Retrieved 2011/02/28.
• 2、 Kluefers, Peter. "Polyol metal complexes. 38. Diammine dihydroxo palladium(II), a new agent for carbohydrate coordination". . p. 2042 - 2044. Retrieved 2008/10/08.