Benzene, 1,1',1''-(1-nitro-1-ethenyl-2-ylidene)tris-

Base Information

• Chemical Name: Benzene, 1,1',1''-(1-nitro-1-ethenyl-2-ylidene)tris-
• CAS No.: 5670-70-2
• Molecular Formula: C20H15NO2
• Molecular Weight: 301.345
• Mol file: 5670-70-2.mol

Synonyms:

Chemical Property of Benzene, 1,1',1''-(1-nitro-1-ethenyl-2-ylidene)tris-

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzene, 1,1',1''-(1-nitro-1-ethenyl-2-ylidene)tris-

There total 18 articles about Benzene, 1,1',1''-(1-nitro-1-ethenyl-2-ylidene)tris- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

Triphenylethylene (58-72-0) → nitro-triphenyl-ethene (5670-70-2)

Guidance literature:

With N–nitrosuccinimide; tris(2,2-bipyridine)ruthenium(II) hexafluorophosphate; In acetonitrile; at 20 ℃; for 6h; Inert atmosphere; Irradiation;

DOI:10.1002/chem.201902966

Reference yield:

Triphenylethylene (58-72-0) → benzophenone (119-61-9) + 1,2,2-triphenylethan-1-one (1733-63-7) + nitro-triphenyl-ethene (5670-70-2) + triphenylacetaldehyde (42365-04-8) + benzaldehyde (100-52-7)

Guidance literature:

With Iron(III) nitrate nonahydrate; oxygen; In dichloromethane; at 150 ℃; for 1h; Microwave irradiation; Sealed tube;

DOI:10.1016/j.tetlet.2018.05.070

Reference yield:

2,2,2-triphenylethylamine (109864-56-4) → nitro-triphenyl-ethene (5670-70-2)

Guidance literature:

With diethyl ether; mixture of gaseous nitrogen oxides; sodium sulfate; at -15 ℃;

DOI:10.1021/ja01304a038

upstream raw materials:

Triphenylethylene

2-diazo-1,1,1-triphenyl-ethane

1,1,2-Triphenylethanol

2,2,2-triphenylethylamine

Downstream raw materials:

1,2,2-triphenylethan-1-one

1,1-Diphenyl-2--2-nitro-aethylen

benzophenone

α-phenylbenzoin

Refernces

• 1、 Zhang, Kun,Jelier, Benson,Passera, Alessandro,Jeschke, Gunnar,Katayev, Dmitry. "Synthetic Diversity from a Versatile and Radical Nitrating Reagent". supporting information. p. 12929 - 12939. Retrieved 2019/09/17.