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2-Methyltetrahydrofuran

Base Information Edit
  • Chemical Name:2-Methyltetrahydrofuran
  • CAS No.:96-47-9
  • Deprecated CAS:74069-67-3
  • Molecular Formula:C5H10O
  • Molecular Weight:86.1338
  • Hs Code.:29321900
  • European Community (EC) Number:202-507-4,246-769-8
  • NSC Number:2115
  • UN Number:2536
  • UNII:FCD0VD8ALF
  • DSSTox Substance ID:DTXSID9030258
  • Nikkaji Number:J49.588C
  • Wikipedia:2-Methyltetrahydrofuran
  • Wikidata:Q209444
  • ChEMBL ID:CHEMBL1580503
  • Mol file:96-47-9.mol
2-Methyltetrahydrofuran

Synonyms:Furan, 2-methyl-tetrahydro-;(2R)-2-methyloxolane;2-Methyloxolane;Tetrahydrosylvan;(2S)-2-methyloxolane;74069-67-3;Furan, tetrahydro-2-methyl-;Tetrahydro-2-methyl-furan;

Suppliers and Price of 2-Methyltetrahydrofuran
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • TRC
  • 2-Methyltetrahydrofuran
  • 10g
  • $ 135.00
  • TRC
  • 2-Methyltetrahydrofuran
  • 25g
  • $ 155.00
  • TCI Chemical
  • 2-Methyltetrahydrofuran (stabilized with BHT) >98.0%(GC)
  • 500mL
  • $ 75.00
  • TCI Chemical
  • 2-Methyltetrahydrofuran (stabilized with BHT) >98.0%(GC)
  • 100mL
  • $ 31.00
  • TCI Chemical
  • 2-Methyltetrahydrofuran (stabilized with BHT) >98.0%(GC)
  • 25mL
  • $ 16.00
  • SynQuest Laboratories
  • 2-Methyltetrahydrofuran 99%
  • 50 mL
  • $ 15.00
  • SynQuest Laboratories
  • 2-Methyltetrahydrofuran 99%
  • 250 mL
  • $ 35.00
  • SynQuest Laboratories
  • 2-Methyltetrahydrofuran 99%
  • 1 L
  • $ 95.00
  • SynQuest Laboratories
  • 2-Methyltetrahydrofuran 99%
  • 5 L
  • $ 295.00
  • Sigma-Aldrich
  • 2-Methyltetrahydrofuran ReagentPlus , ≥99.5%, contains 150-400 ppm BHT as stabilizer
  • 200l
  • $ 7530.00
Total 24 raw suppliers
Chemical Property of 2-Methyltetrahydrofuran Edit
Chemical Property:
  • Appearance/Colour:Clear,colorless liquid 
  • Vapor Pressure:96.8mmHg at 25°C 
  • Melting Point:-136 °C 
  • Refractive Index:n20/D 1.406(lit.)  
  • Boiling Point:79.9 °C at 760 mmHg 
  • Flash Point:10.4°F 
  • PSA:9.23000 
  • Density:0.863 g/cm3 
  • LogP:1.18530 
  • Storage Temp.:Flammables area 
  • Solubility.:150g/l 
  • Water Solubility.:15 g/100 mL (25 C) 
  • XLogP3:1
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:1
  • Rotatable Bond Count:0
  • Exact Mass:86.073164938
  • Heavy Atom Count:6
  • Complexity:43.2
  • Transport DOT Label:Flammable Liquid
Purity/Quality:

99% , *data from raw suppliers

2-Methyltetrahydrofuran *data from reagent suppliers

Safty Information:
  • Pictogram(s): FlammableF,IrritantXi 
  • Hazard Codes:F,Xi 
  • Statements: 11-19-36/37-2017/11/19 
  • Safety Statements: 16-23-39-33-26 
MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:
  • Chemical Classes:Solvents -> Ethers (
  • Canonical SMILES:CC1CCCO1
  • Description 2-Methyltetrahydrofuran (MeTHF or 2-MTHF) is a bio-based solvent that is recognized as the most favorable of ether solvents. The relatively high boiling point (80?C) and low melting point (-137?C) provide a broad temperature range for a myriad of processing conditions. It is a potential greener solvent alternative for organic synthesis. It shows resistance to reduction by lithium making it a promising candidate as electrolytes in lithium batteries. Its polarity and Lewis base strength is intermediate between tetrahydrofuran (THF) and diethyl ether. The ring opening reaction of 2-MTHF has been studied using acid chloride and iodide.
  • Uses 2-Methyltetrahydrofuran acts as a solvent in organic synthesis. It is considered as a replacement for terahydrofuran due to its higher reaction temperature and easy separation after reaction. It is also useful in the electrolyte formulation for secondary lithium electrodes and as a component in alternative fuels. Further, it is used as a solvent for spectroscopic studies at -1960C. It also acts as a solvent for Grignard reagent in organometallic reactions. In addition to this, it plays an important role as a motor fuel. 2-Methyltetrahydrofuran may be used as solvent for phosphatidylserine synthesis.It may be used as an alternative solvent to:DMSO (dimethyl sulfoxide) or MTBE (methyl tertiary butyl ether) in the C-C bond forming reactions catalyzed by lyase enzyme.THF in the reaction between Grignard reagents and carbonyl compounds.Methylene chloride in some biphase reactions. ZerO2 products?are rigorously degassed with highly pure inert gas providing solvents and solutions?(anhydrous if specified)?with very low residual oxygen content.
Technology Process of 2-Methyltetrahydrofuran

There total 291 articles about 2-Methyltetrahydrofuran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
furfural; With hydrogen; at 200 ℃; under 760.051 Torr; Flow reactor;
With hydrogen; at 100 ℃; under 760.051 Torr; Temperature; Flow reactor;
DOI:10.1016/j.catcom.2019.105836
Guidance literature:
Product distribution; Mechanism; Ambient temperature; Irradiation;
DOI:10.1021/jo00186a007
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