2-Propanamine, 2-methyl-N-(triphenylphosphoranylidene)-

Base Information

• Chemical Name: 2-Propanamine, 2-methyl-N-(triphenylphosphoranylidene)-
• CAS No.: 13989-64-5
• Molecular Formula: C22H24 N P
• Molecular Weight: 333.413
• Hs Code.: 2931900090
• NSC Number: 99057
• UNII: JX6QG9L7G9
• DSSTox Substance ID: DTXSID80161188
• Nikkaji Number: J2.731.032J
• Wikidata: Q83029544
• Mol file: 13989-64-5.mol

Synonyms:13989-64-5;N2-(1,1,1-Triphenyl-lambda5-phosphanylidene)-2-methylpropan-2-amine;2-Propanamine, 2-methyl-N-(triphenylphosphoranylidene)-;NSC99057;JX6QG9L7G9;tert-butylimino(triphenyl)-lambda5-phosphane;NSC-99057;2-Methyl-N-(triphenylphosphoranylidene)-2-propanamine;NSC 99057;UNII-JX6QG9L7G9;SCHEMBL9405355;2-Propanamine,2-methyl-N-(triphenylphosphoranylidene)-;DTXSID80161188;N-(tert-Butyl)triphenylphosphine imide;(tert-Butylimino)(triphenyl)phosphorane;tert-butylimino(triphenyl)-$l^{5}-phosphane

Chemical Property of 2-Propanamine, 2-methyl-N-(triphenylphosphoranylidene)-

Chemical Property:

• Vapor Pressure: 4.5E-08mmHg at 25°C
• Boiling Point: 456.1°C at 760 mmHg
• Flash Point: 229.7°C
• PSA: 22.17000
• Density: 1.01g/cm³
• LogP: 4.96260
• XLogP3: 5.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 333.164636767
• Heavy Atom Count: 24
• Complexity: 377

Purity/Quality:

99% ^*data from raw suppliers

N2-(1,1,1-TRIPHENYL-LAMBDA5-PHOSPHANYLIDENE)-2-METHYLPROPAN-2-AMINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)N=P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of 2-Propanamine, 2-methyl-N-(triphenylphosphoranylidene)-

There total 9 articles about 2-Propanamine, 2-methyl-N-(triphenylphosphoranylidene)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dibromotriphenylphosphorane (1034-39-5) → triphenylphosphine-N-tertbutylimine (13989-64-5)

Guidance literature:

Multi-step reaction with 2 steps

1: Et₃N / benzene

2: NaNH₂, liq. NH₃

With ammonia; sodium amide; triethylamine; In benzene;

DOI:10.1021/jo01037a052

Reference yield:

bromure de triphenyl aminophosphonium (15931-69-8) → triphenylphosphine-N-tertbutylimine (13989-64-5)

Guidance literature:

Multi-step reaction with 2 steps

1: n-BuLi / tetrahydrofuran; hexane / 0.5 h / Ambient temperature

2: tetrahydrofuran / 48 h / Heating

With n-butyllithium; In tetrahydrofuran; hexane;

Reference yield:

triphenylphosphine (603-35-0) → triphenylphosphine-N-tertbutylimine (13989-64-5)

Guidance literature:

Multi-step reaction with 3 steps

1: 1.) bromine; 2.) NH₃ / 1.) acetonitrile, 45 min; 2.) acetonitrile, room temp.

2: n-BuLi / tetrahydrofuran; hexane / 0.5 h / Ambient temperature

3: tetrahydrofuran / 48 h / Heating

With n-butyllithium; ammonia; bromine; In tetrahydrofuran; hexane;

upstream raw materials:

tert-butylaminotriphenylphosphonium bromide

lithium triphenylphosphonium azayldiide

tert-Butyl iodide

bromure de triphenyl aminophosphonium

Downstream raw materials:

N-benzylidene tert-butylamine

C₂₂H₂₅BNP

C₂₈H₂₇BNO₂P

C₂₄H₂₉BNP