Cyclohexane, 1-bromo-2-ethoxy-, trans-

Base Information

• Chemical Name: Cyclohexane, 1-bromo-2-ethoxy-, trans-
• CAS No.: 59456-68-7
• Molecular Formula: C₈H₁₅BrO
• Molecular Weight: 207.111
• DSSTox Substance ID: DTXSID80477958
• Wikidata: Q82311057
• Mol file: 59456-68-7.mol

Synonyms:Cyclohexane, 1-bromo-2-ethoxy-, trans-;59456-68-7;DTXSID80477958

Chemical Property of Cyclohexane, 1-bromo-2-ethoxy-, trans-

Chemical Property:

• XLogP3: 2.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 206.03063
• Heavy Atom Count: 10
• Complexity: 95.3

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC1CCCCC1Br
• Isomeric SMILES: CCO[C@@H]1CCCC[C@H]1Br

Technology Process of Cyclohexane, 1-bromo-2-ethoxy-, trans-

There total 5 articles about Cyclohexane, 1-bromo-2-ethoxy-, trans- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

ethanol (64-17-5) + cyclohexene (110-83-8) → trans-1,2-dibromocyclohexane (7429-37-0) + trans-1-bromo-2-ethoxycyclohexane (59456-68-7,60886-86-4,60933-66-6)

Guidance literature:

With Oxone; ammonium bromide; at 20 ℃; for 24h; stereoselective reaction;

DOI:10.1080/00397911.2012.761238

Reference yield:

ethanol (64-17-5) + cyclohexene (110-83-8) → 1,2-dibromocyclohexane (5401-62-7) + trans-1-bromo-2-ethoxycyclohexane (59456-68-7,60886-86-4,60933-66-6)

Guidance literature:

With 2,6-di-tert-butyl-4-methyl-phenol; N,N'-dibromo-2,5-piperazinedione (NBP); In dichloromethane; for 0.5h; Ambient temperature; Irradiation;

DOI:10.1246/bcsj.53.219

Reference yield:

ethanol (64-17-5) + cyclohexene (110-83-8) → trans-1-bromo-2-ethoxycyclohexane (59456-68-7,60886-86-4,60933-66-6)

Guidance literature:

With dibromamine-T; at 20 ℃; for 0.166667h;

DOI:10.1016/j.saa.2011.06.023

upstream raw materials:

ethanol

cyclohexene

Downstream raw materials:

cyclohexyl ethyl ether

2-ethoxycyclohex-1-ene