Morpholine, 4-[3-(diphenylphosphinyl)-1,3-diphenyl-1,2-propadienyl]-

Base Information

Chemical Name:Morpholine, 4-[3-(diphenylphosphinyl)-1,3-diphenyl-1,2-propadienyl]-
CAS No.:602331-08-8
Molecular Formula:C31H28NO2P
Molecular Weight:477.543
Hs Code.:
DSSTox Substance ID:DTXSID40456800
Nikkaji Number:J2.009.022G

Synonyms:602331-08-8;Morpholine, 4-[3-(diphenylphosphinyl)-1,3-diphenyl-1,2-propadienyl]-;DTXSID40456800;3-Morpholino-1,3-diphenylpropadienyldiphenylphosphine oxide

Suppliers and Price of Morpholine, 4-[3-(diphenylphosphinyl)-1,3-diphenyl-1,2-propadienyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of Morpholine, 4-[3-(diphenylphosphinyl)-1,3-diphenyl-1,2-propadienyl]-

Chemical Property:

XLogP3:5.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:6
Exact Mass:477.18576613
Heavy Atom Count:35
Complexity:748

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1COCCN1C(=C=C(C2=CC=CC=C2)P(=O)(C3=CC=CC=C3)C4=CC=CC=C4)C5=CC=CC=C5

Technology Process of Morpholine, 4-[3-(diphenylphosphinyl)-1,3-diphenyl-1,2-propadienyl]-

There total 4 articles about Morpholine, 4-[3-(diphenylphosphinyl)-1,3-diphenyl-1,2-propadienyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 6.0%

: 5796-98-5
bis-trimethylsilanyl peroxide

: 602331-03-3
(3-morpholino-1,3-diphenyl-1,2-propadienyl)diphenylphosphane

: 602331-18-0,861378-82-7
(3-oxo-1,3-diphenyl-1-propenyl)diphenylphosphane oxide

: 602331-08-8
(3-morpholino-1,3-diphenyl-1,2-propadienyl)diphenylphosphane oxide

Guidance literature:: In dichloromethane; for 12h; Title compound not separated from byproducts;
DOI:10.1002/ejoc.200300080

Reference yield:

: 13683-01-7
Diphenylphosphonigsaeure-trimethylsilylester

: 115018-09-2
4-(1,3-Diphenyl-2-propinyliden)morpholinium-trifluormethansulfonat

: 602331-08-8
(3-morpholino-1,3-diphenyl-1,2-propadienyl)diphenylphosphane oxide

Guidance literature:: With lithium chloride; In tetrahydrofuran; at -78 - 20 ℃;
DOI:10.1002/ejoc.200300080

Reference yield:

: 115018-09-2
4-(1,3-Diphenyl-2-propinyliden)morpholinium-trifluormethansulfonat

: 602331-08-8
(3-morpholino-1,3-diphenyl-1,2-propadienyl)diphenylphosphane oxide

Guidance literature:: Multi-step reaction with 2 steps

1: 79 percent / LiCl / tetrahydrofuran / -78 - 20 °C

2: CH₂Cl₂ / 12 h

With lithium chloride; In tetrahydrofuran; dichloromethane;
DOI:10.1002/ejoc.200300080