Technology Process of 2-Propanol, 1-(octadecyloxy)-3-(triphenylmethoxy)-, (S)-
There total 13 articles about 2-Propanol, 1-(octadecyloxy)-3-(triphenylmethoxy)-, (S)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
hydrogen;
Ru2Cl4{(R)-binap}2(C2H5)3N;
In
dichloromethane;
at 20 ℃;
for 96h;
under 73580.8 Torr;
DOI:10.1016/S0040-4039(00)92176-2
- Guidance literature:
-
Multi-step reaction with 6 steps
1: toluene / 1 h / 80 °C
2: pyridine / CHCl3 / Ambient temperature
3: H2 / 5percent Pd/C / tetrahydrofuran / Ambient temperature
4: phosphorus oxychloride, Et3N, pyridine / CHCl3 / Ambient temperature
5: 66 percent / LiAlH4 / tetrahydrofuran / Ambient temperature
6: 81 percent / pyridine / Ambient temperature
With
pyridine; lithium aluminium tetrahydride; hydrogen; triethylamine; trichlorophosphate;
palladium on activated charcoal;
In
tetrahydrofuran; chloroform; toluene;
DOI:10.1002/hlca.19820650339
- Guidance literature:
-
Multi-step reaction with 2 steps
1: pyridinium chlorochromate / CH2Cl2
2: 70 percent / H2 / 2Cl4-((R)-bis(diphenylphosphino-1,1'-binaphthalene)2>NEt3 (Ru(R)BINAP) / CH2Cl2 / 96 h / 20 °C / 73580.8 Torr
With
hydrogen; pyridinium chlorochromate;
Ru2Cl4{(R)-binap}2(C2H5)3N;
In
dichloromethane;
DOI:10.1016/S0040-4039(00)92176-2