132280-81-0Relevant articles and documents
Synthesis of glyceryl ethers in high optical purity via ruthenium catalyzed asymmetric hydrogenation
Cesarotti, Edoardo,Mauri, Angela,Pallavicini, Marco,Villa, Luigi
, p. 4381 - 4384 (1991)
1-O-octadecyl-3-O-trityl-glycerol and 1-O-benzyl-3-O-trityl-glycerol can be prepared by asymmetric catalytic hydrogenation in O.P.> 96% and 87-88% respectively.
Ruthenium-Catalyzed Enantioselective Hydrogenation of 1,3-O-Disubstituted 1,3-Dihydroxypropan-2-ones
Cesarotti, Edoardo,Antognazza, Patrizia,Mauri, Angela,Pallavicini, Marco,Villa, Luigi
, p. 2563 - 2571 (2007/10/02)
Optically active 1,3-O-disubstituted glycerols were obtained by enantioselective homogeneous hydrogenation of the corresponding 1,3-O-disubstituted 1,3-dihyroxypropan-2-ones with different RuII-binap complexes.The highest enantioselectivities w