Phosphine, phenylbis(2,4,6-trimethylbenzoyl)-

Base Information

• Chemical Name: Phosphine, phenylbis(2,4,6-trimethylbenzoyl)-
• CAS No.: 620596-61-4
• Molecular Formula: C26H27O2P
• Molecular Weight: 402.473
• DSSTox Substance ID: DTXSID70469660
• Wikidata: Q82297480
• Mol file: 620596-61-4.mol

Synonyms:Phosphine, phenylbis(2,4,6-trimethylbenzoyl)-;620596-61-4;SCHEMBL132877;DTXSID70469660;phenylbis(2,4,6-trimethylbenzoyl)-phosphine

Chemical Property of Phosphine, phenylbis(2,4,6-trimethylbenzoyl)-

Chemical Property:

• XLogP3: 6.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 402.17486710
• Heavy Atom Count: 29
• Complexity: 515

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC(=C(C(=C1)C)C(=O)P(C2=CC=CC=C2)C(=O)C3=C(C=C(C=C3C)C)C)C

Technology Process of Phosphine, phenylbis(2,4,6-trimethylbenzoyl)-

There total 20 articles about Phosphine, phenylbis(2,4,6-trimethylbenzoyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

C12H17N2O4P + 2-mesitylmagnesium bromide (2633-66-1) → bis-(2,4,6-trimethylbenzoyl)-phenylphosphine (620596-61-4)

Guidance literature:

In tetrahydrofuran; diethyl ether; at 20 ℃; Inert atmosphere;

Reference yield: 98.0%

C12H17N2O4P + mesityllithium (5806-59-7) → bis-(2,4,6-trimethylbenzoyl)-phenylphosphine (620596-61-4)

Guidance literature:

In diethyl ether; tert-butyl methyl ether; at 20 ℃; Inert atmosphere;

Reference yield: 64.0%

Dichlorophenylphosphine (644-97-3) + mesitylene-2-carboxylic acid chloride (938-18-1) → bis-(2,4,6-trimethylbenzoyl)-phenylphosphine (620596-61-4)

Guidance literature:

Dichlorophenylphosphine; mesitylene-2-carboxylic acid chloride; With zinc; In ethyl acetate; at 20 ℃; for 1h; Inert atmosphere;

With dihydrogen peroxide; sodium hydrogencarbonate; In water; ethyl acetate; at 0 - 20 ℃; for 0.833333h;

upstream raw materials:

mesitylene-2-carboxylic acid chloride

iodobenzene

1,2-Diphenyl-1,2-bis(trimethylsilyl)diphosphan

phenylphosphane

Downstream raw materials:

phenyl bis(2,4,6-trimethylbenzoyl)phosphine oxide