Isobutyltriphenylphosphonium iodide

Base Information

• Chemical Name: Isobutyltriphenylphosphonium iodide
• CAS No.: 60610-05-1
• Molecular Formula: C22H24P+
• Molecular Weight: 446.311
• ChEMBL ID: CHEMBL2000775
• NSC Number: 122263
• Mol file: 60610-05-1.mol

Synonyms:isobutyltriphenylphosphonium iodide;NSC122263;SCHEMBL5029340;CHEMBL2000775;OVPOVBJOOFKCFI-UHFFFAOYSA-M;isobutyl triphenylphosphonium iodide;NSC-122263

Chemical Property of Isobutyltriphenylphosphonium iodide

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 13.59000
• Density: g/cm³
• LogP: 1.64050
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 446.06604
• Heavy Atom Count: 24
• Complexity: 284

Purity/Quality:

99% ^*data from raw suppliers

ISOBUTYLTRIPHENYLPHOSPHONIUM BROMIDE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(C)C[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[I-]

Technology Process of Isobutyltriphenylphosphonium iodide

There total 2 articles about Isobutyltriphenylphosphonium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Isobutyl iodide (513-38-2) + triphenylphosphine (603-35-0) → (2-methylpropyl)triphenylphosphonium iodide (60610-05-1)

Guidance literature:

at 120 - 130 ℃;

Reference yield:

chlorobenzene (108-90-7) → (2-methylpropyl)triphenylphosphonium iodide (60610-05-1)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl ether; sodium; phosphorus trichloride / ueber mehrere Stufen

2: 120 - 130 °C

With diethyl ether; sodium; phosphorus trichloride;

Reference yield: 91.0%

(2-methylpropyl)triphenylphosphonium iodide (60610-05-1) + bismuth(III) iodide (7787-64-6) + dimethyl sulfoxide (67-68-5,8070-53-9) → [iso-butyltriphenylphosphonium][Bi2I8(dimethyl sulfoxide)2]

Guidance literature:

In dimethyl sulfoxide; stirring of mixt. of Ph3P(i-Bu)I, BiI3 and DMSO at 20°C for 1 h; concn.; filtration, drying, elem. anal.;

DOI:10.1134/S0036023609020120

upstream raw materials:

Isobutyl iodide

triphenylphosphine

chlorobenzene

Downstream raw materials:

diphenyl 2-methylpropyl phosphine oxide

(E)-1-benzyl-1,4-dihydro-4,7-dimethyl-6-(3-methyl-1-butenyl)-9H-imidazo<1,2-a>purin-9-one

(Z)-1-benzyl-1,4-dihydro-4,6-dimethyl-7-(3-methyl-1-butenyl)-9H-imidazo<1,2-a>purin-9-one

(E)-1-benzyl-1,4-dihydro-4,6-dimethyl-7-(3-methyl-1-butenyl)-9H-imidazo<1,2-a>purin-9-one