Ethyl (1S,2S)-2-(phenylsulfanyl)cyclopropane-1-carboxylate

Base Information

Chemical Name:Ethyl (1S,2S)-2-(phenylsulfanyl)cyclopropane-1-carboxylate
CAS No.:63012-13-5
Molecular Formula:C₁₂H₁₄O₂S
Molecular Weight:222.308
Hs Code.:
DSSTox Substance ID:DTXSID00573724

Synonyms:63012-13-5;DTXSID00573724;Ethyl (1S,2S)-2-(phenylsulfanyl)cyclopropane-1-carboxylate;F96537;REL-ETHYL (1S,2S)-2-(PHENYLTHIO)CYCLOPROPANE-1-CARBOXYLATE

Suppliers and Price of Ethyl (1S,2S)-2-(phenylsulfanyl)cyclopropane-1-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of Ethyl (1S,2S)-2-(phenylsulfanyl)cyclopropane-1-carboxylate

Chemical Property:

XLogP3:2.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:5
Exact Mass:222.07145086
Heavy Atom Count:15
Complexity:224

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C1CC1SC2=CC=CC=C2
Isomeric SMILES:CCOC(=O)[C@@H]1C[C@@H]1SC2=CC=CC=C2

Technology Process of Ethyl (1S,2S)-2-(phenylsulfanyl)cyclopropane-1-carboxylate

There total 8 articles about Ethyl (1S,2S)-2-(phenylsulfanyl)cyclopropane-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 623-73-4
diazoacetic acid ethyl ester

: 1822-73-7
phenylthioethylene

: 63012-12-4,63012-13-5,91496-20-7
ethyl (1S,2R)-2-(phenylsulfanyl)-cyclopropane-1-carboxylate

: ethyl (1R,2S)-2-(phenylsulfanyl)-cyclopropane-1-carboxylate

Guidance literature:: With myoglobin(H₆₄V,V₆₈A,H₉₃NMH)[Fe(2,4-diacetyl deuteroporphyrin IX)]; In ethanol; at 20 ℃; for 16h; pH=7; Reagent/catalyst; Overall yield = 54 percent; Catalytic behavior; Inert atmosphere;
DOI:10.1021/acscatal.9b02272

Reference yield:

: 623-73-4
diazoacetic acid ethyl ester

: 1822-73-7
phenylthioethylene

: 63012-12-4,63012-13-5,91496-20-7
ethyl (1R,2R)-2-(phenylsulfanyl)-cyclopropane-1-carboxylate

: 63012-12-4,63012-13-5,91496-20-7
ethyl (1S,2R)-2-(phenylsulfanyl)-cyclopropane-1-carboxylate

: ethyl (1R,2S)-2-(phenylsulfanyl)-cyclopropane-1-carboxylate

: ethyl (1S,2S)-2-(phenylsulfanyl)-cyclopropane-1-carboxylate

Guidance literature:: With (1R,2R)-(-)-N,N'-bis(3,5-di-tert-butylsalicydene)-1,2-cyclohexanediaminocobalt(II); dimethyl sulfoxide; In water; at 40 ℃; for 24h; Reagent/catalyst; Solvent; Temperature; Overall yield = 100 %Spectr.; stereoselective reaction; Catalytic behavior;
DOI:10.1002/ejoc.201701030

Reference yield:

: 623-73-4
diazoacetic acid ethyl ester

: 1822-73-7
phenylthioethylene

: 63012-12-4,63012-13-5,91496-20-7
ethyl (1R,2R)-2-(phenylsulfanyl)-cyclopropane-1-carboxylate

: 63012-12-4,63012-13-5,91496-20-7
ethyl (1S,2R)-2-(phenylsulfanyl)-cyclopropane-1-carboxylate

: ethyl (1R,2S)-2-(phenylsulfanyl)-cyclopropane-1-carboxylate

: ethyl (1S,2S)-2-(phenylsulfanyl)-cyclopropane-1-carboxylate

Guidance literature:: With (1R,2R)-(-)-N,N'-bis(3,5-di-tert-butylsalicydene)-1,2-cyclohexanediaminocobalt(II); dimethyl sulfoxide; In water; at 40 ℃; for 24h; Reagent/catalyst; Solvent; Temperature; Overall yield = 100 %Spectr.; stereoselective reaction; Catalytic behavior;
DOI:10.1002/ejoc.201701030