57835-99-1

Usage

Uses

Used in Organic Synthesis:
TRIPHENYLSULFONIUM HEXAFLUOROPHOSPHATE is used as a phase-transfer catalyst for facilitating the transfer of a reactant from one phase to another, particularly from an aqueous phase to an organic phase.
Used in Pharmaceutical Production:
TRIPHENYLSULFONIUM HEXAFLUOROPHOSPHATE is used as a catalyst in the production of various pharmaceuticals, agrochemicals, and fine chemicals due to its role in facilitating chemical reactions.

InChI:InChI=1/C18H15S.F6P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7(2,3,4,5)6/h1-15H;/q+1;-1

Upstream product

• 139-66-2 diphenyl sulfide 
• 58109-40-3 diphenyliodonium hexafluorophosphate 

Downstream Products

• 139-66-2 diphenyl sulfide 
• 39950-36-2 [1,1'-biphenyl]-2-yl(phenyl)sulfane 
• 59090-57-2 [1,1'-biphenyl]-4-yl(phenyl)sulfane 
• 113792-74-8 3-phenyldiphenyl sulfide 
• 80621-45-0 triphenylsulphoxonium hexafluorophosphate 
• 1520-42-9 1,1,2-triphenylethane 
• 10170-69-1 dimanganese decacarbonyl 
• 13985-77-8 phenylpentacarbonylmanganese(I) 
• 38551-60-9 Tetraphenyl sulfurane 
• 602-55-1 9-phenylanthracene 
• 1981-38-0 2-phenylanthracene 
• 1714-09-6 1-phenylanthracene 

Relevant academic research and scientific papers

Microwave-assisted formation of sulfonium photoacid generators

Efficient method for preparing sulfonium photoacid generators (PAGs) by microwave-assisted reaction of diarylsufides in the presence of alkylaryliodonium salts. Microwave-assisted synthesis of the PAGs is significantly faster, reducing reaction time with less energy consumption. Reaction times using the microwave-assisted synthesis are in a range of from 90 to 420 faster than conventional thermal conditions. The photoacid quantum yields of several salts prepared by the microwave reaction were measured; the photoacid quantum yields of new sulfonium PAGs were in a range from 0.01 to 0.4 times greater than yields from conventional synthesis. Incorporating a nitro group in the structures of the sulfonium salts increased photoacid quantum yield, induced intersystem crossing and increased the efficiency of photoacid generation compounds.

Characterization of novel sulfonium photoacid generators and their microwave-assisted synthesis

Microwave-assisted synthesis of triarylsulfonium salt photoacid generators (PAGs) afforded reaction times 90 to 420 times faster than conventional thermal conditions, with photoacid quantum yields of new sulfonium PAGs ranging from 0.01 to 0.4. The Royal Society of Chemistry.