rhodium(II)(N,N'-di-4-tolylformidinate)(trifluoroacetato)

Base Information

Chemical Name:rhodium(II)(N,N'-di-4-tolylformidinate)(trifluoroacetato)
CAS No.:105164-41-8
Molecular Formula:C34H34 F6 N4 O6 Rh2
Molecular Weight:914.4583792
Hs Code.:
Mol file:105164-41-8.mol

Synonyms:Rhodium,diaquabis[m-[N,N'-bis(4-methylphenyl)methanimidamidato-N:N']]bis[m-(trifluoroacetato-O:O')]di-,(Rh-Rh), stereoisomer; Acetic acid, trifluoro-, rhodium complex;Methanimidamide, N,N'-bis(4-methylphenyl)-, rhodium complex

Suppliers and Price of rhodium(II)(N,N'-di-4-tolylformidinate)(trifluoroacetato)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of rhodium(II)(N,N'-di-4-tolylformidinate)(trifluoroacetato)

Chemical Property:

PSA：105.56000
LogP:7.62820

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of rhodium(II)(N,N'-di-4-tolylformidinate)(trifluoroacetato)

There total 1 articles about rhodium(II)(N,N'-di-4-tolylformidinate)(trifluoroacetato) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 81229-43-8
{Rh(C₈H₁₂)(N,N'-di-p-tolylformamidinate)}2

: 2966-50-9
silver trifluoroacetate

: 105164-41-8
Rh₂(N,N'-di-p-tolylformamidinate)2(trifluoroacetate)2(H₂O)2*0.5benzene

Guidance literature:: In methanol; dichloromethane; byproducts: Ag; addn. of aq. soln. of AgO2CCF3 to a soln. of the formamidinate complex (protection from light), colour change and pptn., stirring for about 4h (colour became blue-violet; filtration (Celite column), concd. (vac.), violet MeOH adduct compd. deposited (overnight, at room temp.), which gave, on crystn. from a benzene-heptane soln., the water adduct; elem. anal.;

Reference yield: 90.0%

: 105164-41-8
Rh₂(N,N'-di-p-tolylformamidinate)2(trifluoroacetate)2(H₂O)2

: 66224-66-6,66224-67-7,66224-68-8,66224-69-9,134434-48-3,134434-49-4,134454-76-5,134461-75-9
adenine

: 147361-87-3
Rh₂(HC(NC₆H₄CH₃)2)2(O₂CCF₃)2(C₅H₃N₄NH₂)

Guidance literature:: In water; addn. of aq. adenine soln. to acetate soln. of Rh complex in appropriate molar ratio; stirring, room temp., 24h; filtration; evapn. to dryness; washing (twice with water); crystn. (diethyl ether); elem. anal.;
DOI:10.1016/S0020-1693(00)82912-6

Reference yield: 90.0%

: 105164-41-8
Rh₂(N,N'-di-p-tolylformamidinate)2(trifluoroacetate)2(H₂O)2

: 16887-79-9
sodium pyridine-4-carboxylate

: 523999-81-7
[Rh₂(N,N'-di-p-tolylformamidinate)2(isonicotinate)2]

Guidance literature:: In chloroform; water; acetone; (N2); soln. of Rh complex in CHCl3/acetone was added to soln. of salt ofligand in acetone/H2O; mixt. was stirred for 24 h; volatiles removed (vac.); filtered; washed (warm H2O; acetone); dried (vac.); recrystd. (CHCl3/heptane, 3/1); elem. anal.;
DOI:10.1016/S0020-1693(02)01171-4