Silver trifluoroacetate

Base Information

• Chemical Name: Silver trifluoroacetate
• CAS No.: 2966-50-9
• Molecular Formula: C2AgF3O2
• Molecular Weight: 220.884
• Hs Code.: 28432900
• European Community (EC) Number: 221-004-0
• Mol file: 2966-50-9.mol

Synonyms:Aceticacid, trifluoro-, silver(1+) salt (8CI,9CI);Silver mono(trifluoroacetate);Silver perfluoroacetate;Silver trifluoroacetate;Silver(1+)2,2,2-trifluoroacetate;Silver(1+) trifluoroacetate;Silver(I)trifluoroacetate;Trifluoroacetic acid silver(1+) salt;Trifluorooacetic acid,silver salt (1:1);

Chemical Property of Silver trifluoroacetate

Chemical Property:

• Appearance/Colour: light beige to grey crystalline powder
• Vapor Pressure: 96.2mmHg at 25°C
• Melting Point: 257-260 °C (dec.)(lit.)
• Boiling Point: 72.2 °C at 760 mmHg
• PSA: 40.13000
• LogP: -0.70140
• Storage Temp.: Store below +30°C.
• Sensitive.: Hygroscopic
• Water Solubility.: SOLUBLE
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 220.89796
• Heavy Atom Count: 8
• Complexity: 87.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Silver Trifluoroacetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi,T,N
• Hazard Codes: Xi,T,N
• Statements: 36/38-50-36/37/38
• Safety Statements: 26-61-36/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Organic Acids, Metal Salts
• Canonical SMILES: C(=O)(C(F)(F)F)O.[Ag]
• Uses: Silver Trifluoroacetate functions as a catalyst in the synthesis of cyclobutene-fused azepines/dihydropyridines.

Technology Process of Silver trifluoroacetate

There total 9 articles about Silver trifluoroacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

trifluoroacetic acid (76-05-1) + silver(l) oxide (20667-12-3) → silver trifluoroacetate (2966-50-9)

Guidance literature:

at 20 ℃; for 12h;

DOI:10.3762/bjoc.15.239

Reference yield: 74.0%

trifluoroacetic acid (76-05-1) → silver trifluoroacetate (2966-50-9)

Guidance literature:

With silver nitrate; sodium hydroxide; In water;

DOI:10.15227/orgsyn.066.0108

Reference yield:

silver nitrate + trifluoroacetic acid (76-05-1) → silver trifluoroacetate (2966-50-9)

Guidance literature:

silver nitrate; With sodium carbonate; In water; at 20 ℃; for 0.5h;

trifluoroacetic acid;

DOI:10.13005/ojc/310488

upstream raw materials:

trifluoroacetic acid

silver(l) oxide

sodium 2,2,2-trifluoroacetate

Downstream raw materials:

trimethylsilyl trifluoroacetate

methyl-tris-trifluoroacetoxy-silane

cyclohexyl-tris-trifluoroacetoxy-silane

chlorotrifluoromethane

Refernces

• 1、 Smagin,Fadin. "Reaction between silver trifluoroacetate and quercetin in low-polarity organic media". . p. 1085 - 1089. Retrieved 2013.
• 2、 Kaneko, Masao,Ramaraj, Ramasamy,Kira, Akira. "Oxygen Evolution by Means of Water Oxidation Catalyzed by Mononuclear Ruthenium-Ammine Complexes". . p. 417 - 422. Retrieved 1988.
• 3、 Bilibin, A. Yu,Fetin, P. A.,Fetina, V. I.,Lezov, A. A.,Zorin, I. M.. "Impact of counterions on micelle formation and polymerization of 11-acryloyloxyundecyltrimethylammonium surfactants". . . Retrieved 2020/04/20.
• 4、 -. "MANUFACTURING METHOD OF FLUORINATED HYDROCARBON". Paragraph 0060. . Retrieved 2018/05/08.