tert-butyl phenyl sulfoxide

Base Information

• Chemical Name: tert-butyl phenyl sulfoxide
• CAS No.: 4170-71-2
• Molecular Formula: C₁₀H₁₄OS
• Molecular Weight: 182.287
• Mol file: 4170-71-2.mol

Synonyms:

Chemical Property of tert-butyl phenyl sulfoxide

Chemical Property:

• Vapor Pressure: 0.00237mmHg at 25°C
• Boiling Point: 297.6°Cat760mmHg
• Flash Point: 133.8°C
• Density: 1.09g/cm³

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tert-butyl phenyl sulfoxide

There total 71 articles about tert-butyl phenyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

(S)-2-methylpropane-2-sulfinic acid 2,4,6-trimethylbenzyl ester + phenyllithium (591-51-5) → (R)-(tert-butylsulfinyl)benzene (4170-71-2,20696-09-7,62076-10-2,4850-72-0)

Guidance literature:

In tetrahydrofuran; diethyl ether; cyclohexane; at -78 ℃; for 2h;

DOI:10.1021/ol050275p

Reference yield: 98.0%

phenyllithium (591-51-5) + (R)-tert-butyl tert-butanethiosulfinate (67734-35-4) → (tert-butylsulfinyl)benzene (62076-10-2,4170-71-2)

Guidance literature:

In tetrahydrofuran; diethyl ether; cyclohexane; at -78 ℃; for 0.5h;

DOI:10.1021/ja9809206

Reference yield: 96.0%

tert-butyl phenyl sulfide (3019-19-0) → (tert-butylsulfinyl)benzene (62076-10-2,4170-71-2)

Guidance literature:

With 1-methyl-4-(trifluoromethyl)pyrimidinium trifluoromethanesulfonate; dihydrogen peroxide; In methanol; water; at 25 ℃; for 4h; Reagent/catalyst;

DOI:10.1021/jo502865f

upstream raw materials:

tert-butyl phenyl sulfide

1-benzenesulfinyl-4-methyl-benzene

tert.-butyl lithium

propyl benzenesulfinate

Downstream raw materials:

S-Phenyl benzenethiosulfonate

substituted benzenethiol

S-phenyl benzenethiosulfinate

C₁₀H₁₃⁽²⁾HOS