propyl benzenesulfinate

Base Information

• Chemical Name: propyl benzenesulfinate
• CAS No.: 69857-05-2
• Molecular Formula: C₉H₁₂O₂S
• Molecular Weight: 184.259
• Mol file: 69857-05-2.mol

Synonyms:propyl benzenesulfinate

Chemical Property of propyl benzenesulfinate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of propyl benzenesulfinate

There total 7 articles about propyl benzenesulfinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

propan-1-ol (71-23-8) + thiophenol (108-98-5) → propyl benzenesulfinate (69857-05-2)

Guidance literature:

With tetrabutylammonium tetrafluoroborate; In dichloromethane; at 20 ℃; for 20h; Electrochemical reaction; Inert atmosphere; Green chemistry;

DOI:10.1039/c9gc02125f

Reference yield: 58.0%

propan-1-ol (71-23-8) + 1-phenylsulfonyl-2-propanone (5000-44-2) → propyl benzenesulfinate (69857-05-2)

Guidance literature:

With pyridine; oxygen; copper(I) bromide; at 90 ℃; for 6h; Molecular sieve; Schlenk technique;

DOI:10.1002/asia.201701694

Reference yield: 53.0%

propan-1-ol (71-23-8) + benzenesufonyl hydrazide (80-17-1) → propyl benzenesulfinate (69857-05-2)

Guidance literature:

With sodium hydrogensulfite; at 80 ℃; for 6h; Schlenk technique; Green chemistry;

DOI:10.1002/adsc.202001202

upstream raw materials:

propan-1-ol

benzenesulphinyl chloride

diphenyldisulfane

1-phenylsulfonyl-2-propanone

Downstream raw materials:

3-phenylthioindole

S-phenyl cyclohexanecarbothioate

cyclohexyl phenyl sulphide

(tert-butylsulfinyl)benzene

Refernces

• 1、 Zhang, Guofu,Fan, Qiankun,Wang, Huimin,Zhao, Yiyong,Ding, Chengrong. "NaHSO3-Mediated Direct Synthesis of Sulfinic Esters from Sulfonyl Hydrazides under Transition-Metal-Free Conditions". supporting information. p. 833 - 837. Retrieved 2020/12/07.
• 2、 Du, Bingnan,Wang, Wenmin,Wang, Yang,Qi, Zhenghang,Tian, Jiaqi,Zhou, Jie,Wang, Xiaochen,Han, Jianlin,Ma, Jing,Pan, Yi. "Copper-Catalyzed Oxidative Reaction of β-Keto Sulfones with Alcohols via C?S Bond Cleavage: Reaction Development and Mechanism Study". supporting information. p. 404 - 408. Retrieved 2018/02/21.