Arsine oxide, (1-methylpropyl)diphenyl-

Base Information

• Chemical Name: Arsine oxide, (1-methylpropyl)diphenyl-
• CAS No.: 63866-84-2
• Molecular Formula: C16H19AsO
• Molecular Weight: 302.248
• Mol file: 63866-84-2.mol

Synonyms:

Chemical Property of Arsine oxide, (1-methylpropyl)diphenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Arsine oxide, (1-methylpropyl)diphenyl-

There total 4 articles about Arsine oxide, (1-methylpropyl)diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

Diphenyl(propyl)arsanoxid (57831-41-1) + methyl iodide (74-88-4) → sec-Butyldiphenylarsanoxid (63866-84-2)

Guidance literature:

With lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; 1) -20 deg C, 2) 2 h, r.t.;

Reference yield:

chlorodiphenylarsine (712-48-1) → sec-Butyldiphenylarsanoxid (63866-84-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 1) Mg, 2) 30percent aq. H₂O₂ / 1) ether, 2 h, r.t., 2) ether, H₂O

2: 75 percent / LDA / tetrahydrofuran; diethyl ether / 1) -20 deg C, 2) 2 h, r.t.

With dihydrogen peroxide; magnesium; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether;

Reference yield:

chlorodiphenylarsine (712-48-1) + sec.-butyllithium (598-30-1) → sec-Butyldiphenylarsanoxid (63866-84-2)

Guidance literature:

With dihydrogen peroxide; Yield given. Multistep reaction; 1) ether, 2) ether, H₂O, 0 deg C;

upstream raw materials:

chlorodiphenylarsine

sec.-butyllithium

Diphenyl(propyl)arsanoxid

methyl iodide

Downstream raw materials:

1-methylpropyl phenyl sulfide

s-butyl chloride

2-butyl iodide

s-butyl bromide

Refernces