ENDRIN KETONE

Base Information

• Chemical Name: ENDRIN KETONE
• CAS No.: 53494-70-5
• Molecular Formula: C₁₂H₈Cl₆O
• Molecular Weight: 380.913
• Mol file: 53494-70-5.mol

Synonyms:2,5,7-Metheno-3H-cyclopenta[a]pentalen-3-one,3b,4,5,6,6,6a-hexachlorodecahydro-, (2a,3ab,3bb,4b,5b,6ab,7a,7ab,8R*)-; Endrin ketone; SD 2614; d-Ketoendrin

Chemical Property of ENDRIN KETONE

Chemical Property:

• Vapor Pressure: 1.46E-08mmHg at 25°C
• Refractive Index: 1.5550 (estimate)
• Boiling Point: 457.7°C at 760 mmHg
• Flash Point: 2 °C
• PSA: 17.07000
• Density: 1.86g/cm³
• LogP: 3.44730
• Storage Temp.: 2-8°C

Purity/Quality:

98%Min ^*data from raw suppliers

δ-Ketoendrin ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,Xn,T+
• Hazard Codes: F,Xn,T+
• Statements: 11-20/21/22-36-28
• Safety Statements: 16-26-36-45-36/37-28

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of ENDRIN KETONE

There total 11 articles about ENDRIN KETONE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Endrin (72-20-8) → endrin ketone (7378-10-1,53494-70-5)

Guidance literature:

With hydrogenchloride; In dibutyl ether; Heating;

DOI:10.1021/ja01505a024

Reference yield:

1,8-exo-9,10,11,11-Hexachlor-exo-5-formyloxy-pentacyclo<6.2.1.13,6.02,7.04,10>dodecan → endrin ketone (7378-10-1,53494-70-5)

Guidance literature:

Multi-step reaction with 2 steps

1: HCl / ethanol / Heating

2: KMnO₄, aq. H₂SO₄

With hydrogenchloride; potassium permanganate; sulfuric acid; In ethanol;

DOI:10.1021/ja01505a024

Reference yield:

1,2,2,3,10,11-hexachloropentacyclo[5.4.1.03,10.04,12.05,9]dodecan-8-exo-yl acetate → endrin ketone (7378-10-1,53494-70-5)

Guidance literature:

Multi-step reaction with 2 steps

1: HCl / ethanol / Heating

2: KMnO₄, aq. H₂SO₄

With hydrogenchloride; potassium permanganate; sulfuric acid; In ethanol;

DOI:10.1021/ja01505a024

upstream raw materials:

tetrachloromethane

isodrin

phthaloyl peroxide

Endrin

Downstream raw materials:

1,8,9,10,11,11-Hexachlorohexacyclo<6.2.1.1^3,6.0^2,7.0^4,10.0^5,9>dodecan-5-ol

Refernces

• 1、 ApSimon, John W.,Yamasaki, Kazu,Fruchier, Alain,Chau, Alfred S.,Huber, Carol P.. "Apparent carbon-carbon bond cleavage in an epoxide. 2,3,4,5,6-Hexachloro-12-oxopentacyclo8,11.03,10.05,9>tridecane; a minor product from the acid treatment of endrin". . p. 501 - 508. Retrieved 2007/10/02.