17-Iodo-2,5,8,11,14-pentaoxabicyclo[13.4.0]nonadeca-1(15),16,18-triene

Base Information

Chemical Name:17-Iodo-2,5,8,11,14-pentaoxabicyclo[13.4.0]nonadeca-1(15),16,18-triene
CAS No.:69591-40-8
Molecular Formula:C14H19 I O5
Molecular Weight:394.206
Hs Code.:
NSC Number:175878
DSSTox Substance ID:DTXSID20306359
Nikkaji Number:J636.342C
Wikidata:Q82053422

Synonyms:69591-40-8;15-Iodo-2,3,5,6,8,9,11,12-octahydrobenzo[b][1,4,7,10,13]pentaoxacyclopentadecine;17-iodo-2,5,8,11,14-pentaoxabicyclo[13.4.0]nonadeca-1(15),16,18-triene;AH-034/11705213;15-iodo-2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecine;NSC175878;YSZC3664;DTXSID20306359;NSC-175878;E89263;SR-01000395833;SR-01000395833-1

Suppliers and Price of 17-Iodo-2,5,8,11,14-pentaoxabicyclo[13.4.0]nonadeca-1(15),16,18-triene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 7 raw suppliers

Chemical Property of 17-Iodo-2,5,8,11,14-pentaoxabicyclo[13.4.0]nonadeca-1(15),16,18-triene

Chemical Property:

Vapor Pressure:3.96E-08mmHg at 25°C
Boiling Point:457.7°Cat760mmHg
Flash Point:230.6°C
Density:1.442g/cm³
XLogP3:1.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:0
Exact Mass:394.02772
Heavy Atom Count:20
Complexity:254

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1COCCOC2=C(C=C(C=C2)I)OCCOCCO1

Technology Process of 17-Iodo-2,5,8,11,14-pentaoxabicyclo[13.4.0]nonadeca-1(15),16,18-triene

There total 4 articles about 17-Iodo-2,5,8,11,14-pentaoxabicyclo[13.4.0]nonadeca-1(15),16,18-triene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 14098-44-3
2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin

: 69591-40-8
2-iodo-6,7,9,10,12,13,15,16-octahydro-5,8,11,14,17-pentaoxabenzocyclopentadecene

Guidance literature:: With sulfuric acid; iodine; periodic acid; In water; acetic acid; at 70 ℃; for 16h;
DOI:10.3987/COM-06-10831

Reference yield:

: 638-56-2,27252-69-3
1,11-dichloro-3,6,9-trioxaundecane

: 69591-40-8
2-iodo-6,7,9,10,12,13,15,16-octahydro-5,8,11,14,17-pentaoxabenzocyclopentadecene

Guidance literature:: Multi-step reaction with 2 steps

1: 52 percent / aq. NaOH / butan-1-ol / Heating

2: 68 percent / HIO₄; I₂; H₂SO₄ / acetic acid; H₂O / 16 h / 70 °C

With sodium hydroxide; sulfuric acid; iodine; periodic acid; In water; acetic acid; butan-1-ol;
DOI:10.3987/COM-06-10831

Reference yield:

: 112-60-7
Tetraethylene glycol

: 69591-40-8
2-iodo-6,7,9,10,12,13,15,16-octahydro-5,8,11,14,17-pentaoxabenzocyclopentadecene

Guidance literature:: Multi-step reaction with 3 steps

1: 81 percent / SOCl₂; pyridine / benzene / Heating

2: 52 percent / aq. NaOH / butan-1-ol / Heating

3: 68 percent / HIO₄; I₂; H₂SO₄ / acetic acid; H₂O / 16 h / 70 °C

With pyridine; sodium hydroxide; thionyl chloride; sulfuric acid; iodine; periodic acid; In water; acetic acid; butan-1-ol; benzene;
DOI:10.3987/COM-06-10831