Gold, chloro[tris(4-chlorophenyl)phosphine]-

Base Information

Chemical Name:Gold, chloro[tris(4-chlorophenyl)phosphine]-
CAS No.:65295-04-7
Molecular Formula:C18H12AuCl4P
Molecular Weight:598.046
Hs Code.:

Synonyms:

Suppliers and Price of Gold, chloro[tris(4-chlorophenyl)phosphine]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of Gold, chloro[tris(4-chlorophenyl)phosphine]-

Chemical Property:

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Gold, chloro[tris(4-chlorophenyl)phosphine]-

There total 2 articles about Gold, chloro[tris(4-chlorophenyl)phosphine]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: hydrogen tetrachloroaurate(III) tetrahydrate

: 1159-54-2
tri(4-chlorophenyl)phosphine

: 65295-04-7
chloro(tris(4-chlorophenyl)phosphine)gold(I)

Guidance literature:: hydrogen tetrachloroaurate(III) tetrahydrate; With propyl sulfide; In ethanol; at 40 ℃; for 0.166667h;

tri(4-chlorophenyl)phosphine; In ethanol; at 40 ℃; for 1h;
DOI:10.1021/ja311258e

Reference yield: 85.0%

: gold(III) tetrachloride trihydrate

: 1159-54-2
tri(4-chlorophenyl)phosphine

: 65295-04-7
chloro(tris(4-chlorophenyl)phosphine)gold(I)

Guidance literature:: With thiodiglycol; In ethanol; acetone; (N2), HAuCl4*3H2O in EtOH cooled to 0°C, treated with thiodiglycol in EtOH, color vanished, (4-ClC6H4)3P in acetone was added, stirred for 1 h; concd. slowly;

Reference yield:

: 14104-20-2
silver tetrafluoroborate

: 13755-29-8
sodium tetrafluoroborate

: 65295-04-7
chloro(tris(4-chlorophenyl)phosphine)gold(I)

: O{AuP(C₆H₄Cl)3}3⁽¹⁺⁾*BF₄^(1-) = O{AuP(C₆H₄Cl)3}3BF₄

Guidance literature:: With KOH; In tetrahydrofuran; methanol; byproducts: AgCl; AgBF4 in MeOH was added to Au-compound in THF, AgCl filtered off, solution of KOH and NaBF4 in MeOH was added to the filtrate, stirring for 1 h; solvent was removed in vacuo, residue was extracted with CH2Cl2, combined extracts were filtered, ether (large excess) was added;