Trimethyl{[1-(2-methylcyclohex-1-en-1-yl)ethenyl]oxy}silane

Base Information

Chemical Name:Trimethyl{[1-(2-methylcyclohex-1-en-1-yl)ethenyl]oxy}silane
CAS No.:65311-21-9
Molecular Formula:C12H22OSi
Molecular Weight:210.392
Hs Code.:
DSSTox Substance ID:DTXSID00498009
Nikkaji Number:J899.663F
Wikidata:Q82347811

Synonyms:65311-21-9;DTXSID00498009;Trimethyl{[1-(2-methylcyclohex-1-en-1-yl)ethenyl]oxy}silane

Suppliers and Price of Trimethyl{[1-(2-methylcyclohex-1-en-1-yl)ethenyl]oxy}silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Trimethyl{[1-(2-methylcyclohex-1-en-1-yl)ethenyl]oxy}silane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:210.143991855
Heavy Atom Count:14
Complexity:258

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=C(CCCC1)C(=C)O[Si](C)(C)C

Technology Process of Trimethyl{[1-(2-methylcyclohex-1-en-1-yl)ethenyl]oxy}silane

There total 2 articles about Trimethyl{[1-(2-methylcyclohex-1-en-1-yl)ethenyl]oxy}silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 75-77-4
chloro-trimethyl-silane

: 2047-97-4
2-methyl-1-acetyl-1-cyclohexene

: 65311-21-9
trimethyl[1-(2-methyl-1-cyclohexen-1-yl)ethenyloxy]silane

Guidance literature:: 2-methyl-1-acetyl-1-cyclohexene; With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -25 ℃; for 0.333333h;

chloro-trimethyl-silane; In tetrahydrofuran; hexane; at -25 - 20 ℃; for 2h;
DOI:10.1016/S0040-4020(97)10339-8

Reference yield:

: 15564-32-6
1-(2-methyl-cyclohex-2-enyl)-ethanone

: 65311-21-9
trimethyl[1-(2-methyl-1-cyclohexen-1-yl)ethenyloxy]silane

Guidance literature:: Multi-step reaction with 2 steps

1.1: 47.4 g / p-TSA / benzene / 16 h / Heating

2.1: diisopropylamine; n-BuLi / tetrahydrofuran; hexane / 0.33 h / -25 °C

2.2: 93 percent / tetrahydrofuran; hexane / 2 h / -25 - 20 °C

With n-butyllithium; toluene-4-sulfonic acid; diisopropylamine; In tetrahydrofuran; hexane; benzene; 1.1: Isomerization / 2.1: Metallation / 2.2: silylation;
DOI:10.1016/S0040-4020(97)10339-8