Phosphine oxide, dihexylmethyl-

Base Information

• Chemical Name: Phosphine oxide, dihexylmethyl-
• CAS No.: 1831-65-8
• Molecular Formula: C13H29OP
• Molecular Weight: 232.3425
• NSC Number: 222460
• UNII: JPR5M22XG7
• DSSTox Substance ID: DTXSID40171384
• Nikkaji Number: J50.214F
• Mol file: 1831-65-8.mol

Synonyms:Phosphine oxide, dihexylmethyl-;1-[hexyl(methyl)phosphoryl]hexane;1831-65-8;Di-N-hexylmethylphosphine oxide;Dihexyl(methyl)phosphine oxide;NSC 222460;BRN 2412189;JPR5M22XG7;NSC-222460;1-(HEXYL(METHYL)PHOSPHORYL)HEXANE;NSC222460;methyldihexylphosphine oxide;UNII-JPR5M22XG7;C13H29OP;SCHEMBL8327729;DTXSID40171384;DIHEXYLMETHYLPHOSPHINE OXIDE;C13-H29-O-P;LS-105998

Chemical Property of Phosphine oxide, dihexylmethyl-

Chemical Property:

• Vapor Pressure: 5.9E-05mmHg at 25°C
• Boiling Point: 356.7°Cat760mmHg
• Flash Point: 169.5°C
• PSA: 26.88000
• Density: 0.869g/cm³
• LogP: 5.13990
• XLogP3: 4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 10
• Exact Mass: 232.195602542
• Heavy Atom Count: 15
• Complexity: 161

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCP(=O)(C)CCCCCC

Technology Process of Phosphine oxide, dihexylmethyl-

There total 6 articles about Phosphine oxide, dihexylmethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-hexylmagnesium bromide (3761-92-0) → Methyl-dihexyl-phosphinoxid (1831-65-8)

Guidance literature:

Multi-step reaction with 2 steps

2: aq. H₂O₂

With dihydrogen peroxide;

DOI:10.1021/jo01017a055

Reference yield:

Bis--methan (2785-33-3) → Methyl-dihexyl-phosphinoxid (1831-65-8)

Guidance literature:

With lithium aluminium tetrahydride;

DOI:10.1021/ja01468a040

Reference yield:

methyl bromide (74-83-9) → Methyl-dihexyl-phosphinoxid (1831-65-8)

Guidance literature:

With phosphonic acid diethyl ester; In diethyl ether;

DOI:10.1021/jo01036a028

upstream raw materials:

methylphosphonic acid dichloroanhydride

n-hexylmagnesium bromide

Bis--methan

di-n-hexylmethylphosphine

Downstream raw materials:

Di-n-hexyl-<2-hydroxy-2-phenyl-propyl>-phosphinoxid

Di-n-hexyl-<2-hydroxy-2-phenyl-aethyl>-phosphinoxid

Di-n-hexyl-styryl-phosphinoxid

Di-n-hexyl-phenacyl-phosphinoxid