3761-92-0

Basic information

• Product Name: HEXYLMAGNESIUM BROMIDE
• Synonyms: Hexylbromomagnesium;Hexylmagnesium bromide,0.8M solution in THF;Magnesium, bromohexyl-;Hexylmagnesium bromide, 0.8M solution in THF, AcroSeal§3;Hexylmagnesium bromide solution 2.0 in diethyl ether;Hexylmagnesium bromide, 0.8M solution in THF, AcroSeal;HexylMagnesiuM BroMide n-Hexylmagnesium bromide 1M solution in THF
• CAS NO: 3761-92-0
• Molecular Formula: C₆H₁₃BrMg
• Molecular Weight: 189.38
• Product Categories: Synthetic Organic Chemistry;Typical Metal Compounds;AlkylChemical Synthesis;Grignard Reagents;Organic Bases;Organometallic Reagents;Synthetic Reagents;Grignard Reagent;Indolines ,Indoles ,Indazoles;Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds
• Mol File: 3761-92-0.mol
• Article Data: 4

Chemical Properties

• Flash Point: -40 °C
• Appearance: Brown/Liquid
• Density: 0.97 g/mL at 20 °C
• BRN: 3535624
• CAS DataBase Reference: HEXYLMAGNESIUM BROMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: HEXYLMAGNESIUM BROMIDE(3761-92-0)
• EPA Substance Registry System: HEXYLMAGNESIUM BROMIDE(3761-92-0)

Safety Data

• Hazard Codes: F+,C,F
• Statements: 12-14-22-34-66-67-19-11
• Safety Statements: 16-26-36/37/39-43-45-7/8-33-29-8
• RIDADR: UN 2924 3/PG 1
• WGK Germany: 1
• F: 1-3-10
• HazardClass: 4.2
• PackingGroup: I
• Hazardous Substances Data: 3761-92-0(Hazardous Substances Data)

Usage

Chemical Properties

Brown solution

InChI:InChI=1/C6H13.BrH.Mg/c1-3-5-6-4-2;;/h1,3-6H2,2H3;1H;/q;;+1/p-1/rC6H13Mg.BrH/c1-2-3-4-5-6-7;/h2-6H2,1H3;1H/q+1;/p-1

Upstream product

• 111-25-1 1-bromo-hexane 

Downstream Products

• 111-87-5 octanol 
• 67267-87-2 (+/-)-6-hydroxy-6-phenyl-dodecane 
• 2847-72-5 4-methyldecane 
• 21964-44-3 non-1-en-3-ol 
• 92-52-4 biphenyl 
• 112-40-3 dodecane 
• 1077-16-3 hexylbenzene 
• 24796-87-0 2-bromo-cyclohexanol 
• 95061-32-8 1-Cyclopentyl-2-nonyl-1-ol 
• 108535-33-7 (R)-(+)-1,1,1-trifluoro-2-decanol 
• 111423-27-9 (S)-(-)-(1-trifluoromethyl)nonanol 
• 10217-65-9 Dihexyl-quecksilber 
• 100863-37-4 1-(3-methoxyphenyl)heptan-1-one 
• 18297-98-8 dihexyl-phenyl-phosphine 

Relevant articles and documents

Chromium(II)-Catalyzed Diastereoselective and Chemoselective Csp2-Csp3 Cross-Couplings Using Organomagnesium Reagents

A simple protocol for performing chromium-catalyzed highly diastereoselective alkylations of arylmagnesium halides with cyclohexyl iodides at ambient temperature has been developed. Furthermore, this ligand-free CrCl2 enables efficient electrophilic alkenylations of primary, secondary, and tetiary alkylmagnesium halides with readily available alkenyl acetates. Moreover, this chemoselective C-C coupling reaction with stereodefined alkenyl acetates proceeds in a stereoretentive fashion. A wide range of functional groups on alkyl iodides and alkenyl acetates are well tolerated, thus furnishing functionalized Csp2-Csp3 coupling products in good yields and high diastereoselectivity. Detailed mechanistic studies suggest that the in situ generated low-valent chromium(I) species might be the active catalyst for these Csp2-Csp3 cross-couplings.

Method for producing alkyl-bridged ligand systems and transition metal compounds

The invention relates to a method for producing highly substituted alkyl-bridged ligand systems on the basis of indene derivatives and transition metal compounds. Said alkyl-bridged ligand systems can be obtained in high yields using this method.